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  • Produktbild: Electron Transfer Reactions in Organic Chemistry
  • Produktbild: Electron Transfer Reactions in Organic Chemistry
Band 25

Electron Transfer Reactions in Organic Chemistry

Aus der Reihe Reactivity and Structure: Concepts in Organic Chemistry

Fr. 137.00

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

22.11.2011

Verlag

Springer Berlin

Seitenzahl

234

Maße (L/B/H)

24.4/17/1.4 cm

Gewicht

441 g

Auflage

Softcover reprint of the original 1st ed. 1987

Sprache

Englisch

ISBN

978-3-642-72546-3

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

22.11.2011

Verlag

Springer Berlin

Seitenzahl

234

Maße (L/B/H)

24.4/17/1.4 cm

Gewicht

441 g

Auflage

Softcover reprint of the original 1st ed. 1987

Sprache

Englisch

ISBN

978-3-642-72546-3

Herstelleradresse

Springer-Verlag GmbH
Tiergartenstr. 17
69121 Heidelberg
DE

Email: GPSR Kontakt

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  • Produktbild: Electron Transfer Reactions in Organic Chemistry
  • Produktbild: Electron Transfer Reactions in Organic Chemistry
  • I Electron Transfer, a Neglected Concept in Organic Chemistry.- I.1 Electron Transfer is Fundamental in Many Areas of Organic Chemistry.- I.2 Organic Electron Transfer Theories Come in Cycles.- I.3 References.- II Concepts and Definitions.- II.1 Electron Transfer Can Be Defined in Several Ways.- II.2 Inner-and Outer-sphere Electron Transfer.- II.3 Other Concepts in Electron Transfer Chemistry.- II.4 References.- III Theories of Electron Transfer in Organic Chemistry.- III.1 The Thermodynamic Approach to Electron Transfer Reactivity.- III.2 The Single Electron Shift, a Configuration Mixing Model of Electron Transfer Reactivity.- III.3 The Marcus Theory for Outer-sphere ET.- III.3.a The Physical Model.- 111.3. b The Marcus Equation.- III.3.c Properties of the Marcus Expression.- III. 4 Kinetic Models of Electron Transfer Mechanisms.- III.4.a The Collide-and React Model.- III.4.b The Kinetic Model of Reversible Electron Transfer.- III.5 The Marcus Inverted Region.- III.6 The Rehm-Weiler and Agmon-Levine Equations.- III.7 References.- IV How to Use the Marcus Theory.- IV.1 Standard Potential.- IV.2 Reorganization Energy.- IV.3 Case Studies.- IV.3.a Oxidation of Alkylmetals by Fe(III) Complexes.- IV.3.b Oxidation of NADH by Ferrieinium Ions.- IV.3.c Reduction of N-bromosuccinimide by Ferrocenes and Other Easily Oxidizable Compounds.- IV.4 References.- V Experimental Diagnosis.- V.l Phenomenological Approach.- V.2 Mechanistic Approach.- V 2.a Detection of Radicals by ESR Spectroscopy.- V.2.b Trapping of Radical Intermediates.- V.2.c Stereochemistry.- V.2.d Formation of Radical-derived Products.- V.2.e Kinetic Methods.- V.2.f Isotope Effects.- V.2.g Failures of Simple LFERs.- V.2.h Comparison with Compulsory ET Reactions.- V.2.i Photostimulation.- V.2.j Appearance of Charge-transfer Complexes.- V.2.k Chemiluminescence.- V.3 Summarizing Remarks.- V.4 References.- VI Reactions Between Organic and Inorganic Non-metallic Species.- V.1 Oxygen Derived Species.- VI.2 Sulfur Derived Species.- VI.3 Nitrogen Derived Species.- VI.4 Halogen Derived Species.- VI.5 Miscellaneous.- VI.6 Summarizing Remarks.- IV.7 References.- VII Reaction Between Organic and Metal Ion Species.- VII.1 One-and Two-electron Reagents.- VII.2 Choice of Metal Reagent and Substrate in Mechanistic Studies.- VII.3 Examples of Established Outer-sphere Mechanisms.- VII.4 Specific Systems.- VII.4.a Co(III) Oxidation.- VII.4.b Mn(III) Oxidation.- VII.4.c Ag(II) Oxidation.- VII.4.d Cu(III) Oxidation.- VII.4.e Cu(II) Oxidation.- VII.4.f Ce(IV) Oxidation.- VII.4.g Ir(IV) Oxidation.- VII.4.h Ni(IV) and Ni(III) Oxidation.- VII.4.i Tl(III) Oxidation.- VII.4.j Pb(IV) Oxidation.- VII.4.k Pd(II) Oxidation.- VII.5 Conclusion.- VII.6 References.- VIII Electron Transfer Reactions Between Organic Species.- VIII. 1 Radical Ions and Radicals as ET Reagents.- VIII.1.a Reduction of Halides by Radical Anions.- VIII.l.b Reduction of Halides by Metal Reagents.- VIII.1.c Reduction of Polyhalides by ET Reagents.- VIII.l.d Reaction Between Radical Cations and Carboxylate Ions.- VIII.l.e ET Reactions Between Radicals and Neutral Organic Species.- VIII.2 Organic Ions and Even-electron Molecules as ET Reagents.- VIII.2.a Carbanions as ET Reductants.- VIII.2.b Alkyllithiums and Grignard Reagents as ET Reagents.- VIII.2.c Other Main Group Organometallics as ET Reagents.- VIII.2.d NADH as a Potential ET Reagent.- VIII.2.e Peroxide Derivatives as ET Oxidants.- VIII.3 References.- IX Electricity and Light Promoted ET.- IX.1 Organic Electrode Processes.- IX.1.a An Overview of the Electrochemical Process.- IX.l.b The Nature of the Electrode/Electrolyte Interface.- IX.l.c The Activation Process of an Outer-Sphere Electrochemical Step.- IX.l.d Outer-sphere ET, the Sledgehammer Approach to Redox Chemistry.- IX.l.e Electrocatalysis.- IX.2 Photochemical ET.- IX.2.a A Simple MO Picture of Photochemical ET.- IX.2.b Application of the Marcus and Rehm-Weller Treatments to Photochemical ET.- IX.2.c Chemical Consequences of Photochemical ET or how to Avoid the Back ET Reaction.- IX.2.d Aromatic Photocyanation.- IX.2.e Photosolvolysis and Photo Wagner-Meerwein Rearrangement via Intramolecular ET.- IX.2.f Photoexcitation of Electron Donor-acceptor Complexes.- IX. 3 Photoelectrochemistry.- IX.4 Chemiluminescence.- IX.5 References.- X Electron Transfer Catalyzed Reactions.- X.1 Electron Transfer Catalysis as a General Phenomenon.- X.2 An Overview of the ETC Process.- X.3 Different Types of ETC Reactions.- X.3.a The SRN1 Mechanism.- X.3.b The SRE2 Mechanism.- X.3.c The SOE1 Mechanism.- X.3.d The SON2 Mechanism.- X.3.e ET Catalyzed Decomposition of Diazo Compounds.- X.3.f ET Catalyzed Cycloadditions.- X.3.g ET Catalyzed Addition of Dioxygen.- X.3.h ET Catalyzed Cycloreversions.- X.3.i ET Catalyzed Reactions of Strained Heterocyclic Systems.- X.3.j ET Catalyzed Rotation Around Bonds.- X.3.k ET Catalyzed Reactions of Organometallics.- X.4 References.- XI ET and Polar Mechanisms; How Are They Connected?.- XI.1 Formulation of the Problem.- XI. 2 Electrophilic Aromatic Substitution.- XI.2.a The Single Electron Shift Hypothesis as Governing Electrophilic Reactivity.- XI.2.b Does Outer-sphere ET Take Place in Electrophilic Aromatic Substitution?.- XI.3 The SN2 Mechanism.- XI.4 Conclusions.- IX.5 References.- XII Applications of Outer-sphere Electron Transfer.- XII.1 Introduction.- XII.2 Photochemical Fuel Production.- XII.3 Light from Chemical Reactions (Chemiluminescence).- XII.4 Synthetic Applications of ET Reactions.- XII. 5 Conducting Organic Materials.- XII.5.a Radical Cation Salts, Conductors and Superconductors.- XII.5.b ET Oxidized or Reduced Polymers.- XII.5. c The Marcus Theory in Relation to Conducting Organic Materials.- XII.5.d An Organic Chemist’s Model of a Conducting Polymer.- XII.6 Molecular Electronic Devices of Organic Origin.- XII.7 Oscillating Reactions.- XII.8 Wood Pulping and ET.- XII.9 Toxicity and ET.- XII.10 Degradation Mechanisms of Organic Compounds.- XII.11 References.- Epilogue.