Produktbild: The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide

The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide

Fr. 72.90

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Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

07.12.2011

Verlag

Springer Berlin

Seitenzahl

232

Maße (L/B/H)

24.4/17/1.4 cm

Gewicht

435 g

Auflage

Softcover reprint of the original 1st ed. 1984

Sprache

Englisch

ISBN

978-3-642-69664-0

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

07.12.2011

Verlag

Springer Berlin

Seitenzahl

232

Maße (L/B/H)

24.4/17/1.4 cm

Gewicht

435 g

Auflage

Softcover reprint of the original 1st ed. 1984

Sprache

Englisch

ISBN

978-3-642-69664-0

Herstelleradresse

Springer-Verlag KG
Sachsenplatz 4-6
1201 Wien
AT

Email: GPSR Kontakt

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  • Produktbild: The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide
  • 1 Introduction.- 1.1 References.- 2 Transition Metal-Hydrogen Interactions.- 2.1 Reaction of Hydrogen with Transition Metal Complexes and Surfaces.- 2.2 Metal-Hydrogen Bond Energy.- 2.3 Different Types of Metal-Hydrogen Bonding and the M-H Bond Length.- 2.4 Polarity of the M-H Bond.- 2.5 Mobility of Hydrogen Ligands.- 2.6 Conclusion.- 2.7 References.- 3 Transition Metal-Carbon Monoxide Interactions.- 3.1 The CO Molecule.- 3.2 Coordination Chemistry of CO in Molecular Complexes and Clusters.- 3.3 Molecular Carbon Monoxide on Metal Surfaces.- 3.4 CO Dissociation on Metal Surfaces.- 3.5 Conclusion.- 3.6 References.- 4 Non-Catalytic Interaction of CO with H2.- 4.1 On Metal Surfaces.- 4.2 CO/H2 Interaction in Transition Metal Complexes.- 4.2.1 Hydridocarbonyl Complexes.- 4.2.2 Formyl Complexes.- 4.2.3 Formaldehyde Complexes.- 4.2.4 A Methoxy Complex.- 4.2.5 Carbide Complexes.- 4.3 Conclusions.- 4.4 References.- 5 Key Reactions in Catalysis.- 5.1 Oxidative Addition.- 5.2 Reductive Elimination.- 5.2.1 Intramolecular Reductive Elimination.- 5.2.2 Intermolecular Reductive Elimination.- 5.3 Migratory Insertion Reactions.- 5.3.1 CO Insertion into Metal-Alkyl Bonds.- 5.3.2 Alkyl Migration versus CO Migration.- 5.3.3 Promotion of Migratory CO Insertion.- 5.3.4 Absence of Acyl-to-CO Migration.- 5.3.5 CO Insertion into Metal-H Bonds.- 5.3.6 Migratory Insertions involving Carbene Ligands.- 5.3.7 Olefin Insertion.- 5.3.8 Coinsertion of Ethylene and CO.- 5.3.9 Insertion of Formaldehyde.- 5.4 Hydrogen Eliminiation Reactions.- 5.4.1 ?-Hydrogen Elimination.- 5.4.2 ?-Elimination of Hydrogen.- 5.4.3 ?- and ?-Elimination of Hydrogen.- 5.5 Ligand Influences.- 5.5.1 In Molecular Complexes.- 5.5.2 On Metal Surfaces.- 5.6 Conclusion.- 5.7 References.- 6 Catalysts and Supports.- 6.1 Molecular Complexes and Metal Surfaces — Analogies and Differences.- 6.2 Supported Metal Catalysts.- 6.2.1 Metals and Supports Used for CO Hydrogenation.- 6.2.2 Metal-Support Interactions.- 6.2.3 Steric Constraints in Zeolites.- 6.3 Conclusions.- 6.4 References.- 7 Methanation.- 7.1 Carbide Mechanism.- 7.2 CO Insertion Mechanism.- 7.3 Inverse H/D Isotope Effects.- 7.4 Conclusion.- 7.5 References.- 8 Methanol from CO + H2.- 8.1 Nondissociative Incorporation of CO.- 8.2 Homogeneous Methanol Formation.- 8.3 Methanol Synthesis with Supported Noble Metal Catalysts.- 8.4 Synergism in the Cu/ZnO Catalyst.- 8.5 Conclusions.- 8.6 References.- 9 Fischer-Tropsch Synthesis.- 9.1 Early Developments and Present State of Commercial Fischer-Tropsch Synthesis.- 9.2 The Products of the FT Synthesis.- 9.2.1 Primary Products.- 9.2.2 Secondary Reactions of the ?-Olefins.- 9.2.3 Modified FT Synthesis.- 9.3 Distribution of Molecular Weights.- 9.3.1 The Schulz-Flory Distribution Function.- 9.3.2 Experimental Molecular Weight Distributions.- 9.4 Kinetics and Thermodynamics of the FT Reaction.- 9.5 Reaction Mechanism.- 9.5.1 Suggested Mechanisms.- 9.5.2 The Carbide Theory in the Light of Homogeneous Coordination Chemistry.- 9.5.3 Details and Support for the CO Insertion Mechanism.- 9.5.4 The Chain Initiating Step.- 9.5.5 Secondary Reactions.- 9.6 Influence of the Dispersity of Metal Centers.- 9.7 Influence of the Temperature and Pressure.- 9.7.1 Hydrocarbons versus Oxygenates.- 9.7.2 The Particular Case of Ruthenium Catalysts.- 9.8 The Role of Alkali Promoters.- 9.9 Product Selectivity.- 9.9.1 Consequences of the Schulz-Flory Molecular Weight Distribution.- 9.9.2 Deviations from the Schulz-Flory Distribution.- 9.10 Conclusion.- 9.11 References.- 10 Homogeneous CO Hydrogenation.- 10.1 Hydroformylation of Olefins (Oxo Reaction).- 10.2 Hydroformylation of Formaldehyde.- 10.3 Polyalcohols from CO + H2, and Related Homogeneous Syntheses.- 10.4 Conclusion.- 10.5 References.- 11 Methanol as Raw Material.- 11.1 Carbonylation of Methanol (Acetic Acid Synthesis)..- 11.2 Methanol Homologation.- 11.3 Hydrocarbons from Methanol Dehydration and Condensation.- 11.4 Conclusion.- 11.5 References.- 12 Attempt of a Unified View.- 12.1 References.- 13 Subject Index.