Band 3
Aspects of Homogeneous Catalysis A Series of Advances
Aus der Reihe
Aspects of Homogeneous Catalysis
-
- Hardcover
- Taschenbuch ausgewählt
- eBook
-
Sprache:Englisch
-
Auflage:Softcover reprint of the original 1st ed. 1977
- Softcover reprint of the original 1st ed. 1990 Fr. 137.00
- Softcover reprint of the original 1st ed. 1984 Fr. 72.90
- Softcover reprint of the original 1st ed. 1981 Fr. 72.90
- Softcover reprint of the original 1st ed. 1970 Fr. 72.90
- Softcover reprint of the original 1st ed. 1988 Fr. 72.90
- Softcover reprint of the original 1st ed. 1977 Fr. 72.90 ausgewählt
- Softcover reprint of the original 1st ed. 1974 Fr. 72.90
Fr. 72.90
inkl. gesetzl. MwSt.,
Beschreibung
Produktdetails
Einband
Taschenbuch
Erscheinungsdatum
09.10.2011
Herausgeber
R. UgoVerlag
Springer NetherlandSeitenzahl
249
Maße (L/B/H)
24.4/17/1.5 cm
Gewicht
448 g
Auflage
Softcover reprint of the original 1st ed. 1977
Sprache
Englisch
ISBN
978-94-010-1201-0
In recent years, the liquid phase oxidation of organic substrates using transition metal compounds as catalysts has become a profitable means of obtaining industrially important chemicals. Millions of tons of valuable petrochemicals are produced in this manner annually [1]. Typical examples of such processes are the production of vinyl acetate or acetaldehyde via the Wacker process, equations (1) and (2); the Mid Century process for the oxidation of methyl aromatics, such as p-xylene to tereph thalic acid, equation (3); and the production of propylene oxide from propylene using alkyl hydroperoxides, equation (4). PdCI , CuCI 2 2 (1) CH2 = CH2 + 1/2 O2 -H 0 ~ CH3CHO 2 (2) Co(OAcjz ~ (3) (4) The vast majority of liquid phase transition metal catalyzed oxidations of organic compounds fall into these three broad categories: (a) free radical autoxidation reactions, (b) reactions involving nucleophilic attack on coordinated substrate such as the Wacker process, or (c) metal catalyzed reactions of organic substrates with hydroperoxides. Of these three classes of oxidations only the first represents the actual interaction of dioxygen with an organic substrate. The function of oxygen in the Wacker process is simply to re-oxidize the catalyst after each cycle [2].
Kundinnen und Kunden meinen
Verfassen Sie die erste Bewertung zu diesem Artikel
Helfen Sie anderen Kund*innen durch Ihre Meinung