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  • Produktbild: New Pathways for Organic Synthesis
  • Produktbild: New Pathways for Organic Synthesis

New Pathways for Organic Synthesis Practical Applications of Transition Metals

Fr. 72.90

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

01.10.2011

Verlag

Springer Us

Seitenzahl

468

Maße (L/B/H)

22.9/15.2/2.6 cm

Gewicht

678 g

Auflage

Softcover reprint of the original 1st ed. 1984

Sprache

Englisch

ISBN

978-1-4612-9653-9

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

01.10.2011

Verlag

Springer Us

Seitenzahl

468

Maße (L/B/H)

22.9/15.2/2.6 cm

Gewicht

678 g

Auflage

Softcover reprint of the original 1st ed. 1984

Sprache

Englisch

ISBN

978-1-4612-9653-9

Herstelleradresse

Springer-Verlag KG
Sachsenplatz 4-6
1201 Wien
AT

Email: GPSR Kontakt

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  • Produktbild: New Pathways for Organic Synthesis
  • Produktbild: New Pathways for Organic Synthesis
  • 1. Introduction.- 2. Formation of Carbon—Carbon Bonds.- 2.1. Formation of Carbon—Carbon Single Bonds.- 2.1.1. Preparation of Substituted Alkenes.- 2.1.2. Dienes and Polyenes.- 2.1.3. Substituted Alkynes.- 2.1.4. Substituted Arenes.- 2.1.5. Substituted Alkanes (By Conjugate Addition of Organocopper Reagents to Activated Alkenes).- 2.2. Formation of Carbon—Carbon Double Bonds.- 2.2.1. Catalytic Alkene Metathesis.- 2.2.2. Dehalogenation of vic-Dihalides and Coupling of gem-Dihalides, Aldehydes, and Ketones.- 2.2.3. Deoxygenation of Epoxides.- 3. Formation of Carbocyclic Compounds.- 3.1. Introduction.- 3.2. Formation of Three-Membered Rings.- 3.2.1. Carbene Addition to Alkenes or Alkynes.- 3.2.2. Cyclization Reactions.- 3.3. Formation of Four-Membered Rings.- 3.3.1. 2?-2? Cycloaddition of Alkenes.- 3.3.2. Cyclization Reactions.- 3.4. Formation of Five-Membered Rings.- 3.4.1. Cycloaddition Reactions Involving Alkenes, Alkynes, and Dienes.- 3.4.2. Cycloaddition of Two Unsaturated Species with a Third Substrate.- 3.4.3. Cyclization of Difunctional Substrates.- 3.5. Formation of Six-Membered Rings.- 3.5.1. Alkyne Trimerization—Formation of Aromatic Rings.- 3.5.2. Formation of Nonaromatic Six-Membered Rings from Alkynes.- 3.5.3. Cyclotrimerization of Alkenes and Allenes.- 3.5.4. Cyclodimerization of Dienes and Trienes.- 3.5.5. Cycloaddition of Dienes to Alkenes or Alkynes.- 3.5.6. Cyclization of Difunctional Substrates.- 3.6. Formation of Seven-Membered Rings.- 3.6.1. 3?–4? Cycloaddition Reactions.- 3.6.2. Cyclization of Difunctional Substrates.- 3.7. Formation of Eight-Membered Rings.- 3.7.1. Cyclodimerization of 1,3 Dienes.- 3.7.2. Cyclotetramerization of Alkynes.- 3.8. Formation of Large Rings (?9).- 3.8.1. Cycloaddition Reactions.- 3.8.2. Intramolecular Coupling.- 4. Formation of Heterocyclic Compounds.- 4.1. Introduction.- 4.2. Nitrogen Heterocycles.- 4.2.1. Three-Membered Rings.- 4.2.2. Four-Membered Rings.- 4.2.3. Five-Membered Rings.- 4.2.4. Six-Membered Rings.- 4.2.5. Seven-Membered Rings.- 4.3. Oxygen Heterocycles.- 4.3.1. Five-Membered Rings.- 4.3.2. Six-Membered Rings.- 4.4. Sulfur Heterocycles.- 4.5. Cyclic Compounds Containing Two Hetero Atoms.- 5. Isomerization of Alkenes.- 5.1. Introduction.- 5.2. Thermodynamic Considerations.- 5.3. Isolation of Organometallic Intermediates.- 5.4. Mechanisms of Catalytic Alkene Isomerization.- 5.5. Formation of a,?-Unsaturated Compounds.- 5.5.1. Propenyl Ethers from Allyl Ethers.- 5.5.2. ?,?-Unsaturated Aldehydes and Ketones from Diallyl Ethers.- 5.5.3. Ketones from Allylic Alcohols.- 5.5.4. Enamines from Allylamines.- 5.5.5. Propenylamides from N-Allylamines.- 5.5.6. a,?-Unsaturated Cyclic Ketones via Remote Double-Bond Migration.- 5.5.7. Intercoriversion of a,?-Unsaturated Ketones.- 5.6. Formation of Conjugated Dienes.- 5.7. Migration into Conjugation with Aromatic Rings.- 5.8. Formation of Aromatic Compounds—Isoaromatization.- 5.8.1. Formation of Substituted Phenols.- 5.8.2. Formation of Hydroxytropolones.- 5.8.3. Formation of Substituted Anilines.- 6. Direct Introduction and Removal of Carbonyl Groups.- 6.1. Preliminaries.- 6.2. Preparation of Carboxylic Acids, Esters, and Related Derivatives.- 6.2.1. Carboxylic Acids.- 6.2.2. Esters.- 6.2.3. Preparation of Amides.- 6.2.4. Preparation of Anhydrides.- 6.2.5. Preparation of Acyl Halides.- 6.3. Preparation of Aldehydes.- 6.3.1. Aldehydes: From Halides.- 6.3.2. Aldehydes: From Alkenes.- 6.3.3. Aldehydes: From Aldehydes and Silanes.- 6.4. Preparation of Ketones.- 6.4.1. Ketones: From Halides.- 6.4.2. Ketones: From Alkenes and Alkynes.- 6.4.3. Ketones: From Organomercury Compounds.- 6.5. Preparation of Isocyanates.- 6.6. Decarbonylation of Aldehydes and Acyl Halides.- 7. Reduction.- 7.1. Introduction.- 7.1.1. Hydrogenation.- 7.1.2. Transfer Hydrogenation.- 7.1.3. Transition Metal—Metal Hydride Reductions.- 7.2. Reduction of Triple Bonds.- 7.2.1. Formation of Alkanes.- 7.2.2. Formation of Alkenes.- 7.2.3. Selective Reductions.- 7.2.4. Formation of Polyunsaturated Species by Partial Reduction.- 7.3. Reduction of Double Bonds (Nonaromatic).- 7.3.1. Formation of Alkanes.- 7.3.2. Partial Reduction of Polyunsaturated Substrates.- 7.3.3. Reduction of Unsaturated Aldehydes and Ketones.- 7.4. Reduction of Aromatic Systems.- 7.4.1. Formation of Cycloalkanes.- 7.4.2. Partial Reduction of Aromatic and Polyaromatic Compounds.- 7.5. Reduction of Carbonyl Groups.- 7.5.1. Formation of Alcohols from Aldehydes and Ketones.- 7.5.2. Selective Reduction of Aldehydes and Ketones.- 7.5.3. Reduction of Carboxylic Acids and Acid Derivatives.- 7.6. Reduction of Nitro, Nitrile, and Other Nitrogen-Containing Functional Groups.- 7.6.1. Reduction of Nitro Groups.- 7.6.2. Partial Reduction of the Nitro Group.- 7.6.3. Selective Reduction of Nitro Compounds.- 7.6.4. Reduction of the Nitrile Functional Group.- 7.6.5. Formation of Mixed Amines from Nitriles.- 7.6.6. Selective Reduction of the Nitrile Group.- 7.6.7. Reduction of Oximes, Imines, and Nitroso Groups.- 7.7. Asymmetric Hydrogenation.- 7.7.1. Heterogeneous Catalysts.- 7.7.2. Homogeneous Catalysts.- 7.7.3. Mechanism of Asymmetric Hydrogenation.- 7.7.4. Asymmetric Hydrogenation of a-Acylaminoacrylic Acids.- 7.7.5. Optically Active Alcohols from Asymmetric Hydrogenation of Ketones.- 7.7.6. Asymmetric Hydrosilylation.- 7.8. Hydrogenolysis.- 7.8.1. Dehalogenation.- 7.8.2. Selective Reduction of Polyhalo Compounds.- 7.8.3. Hydrogenolysis of Benzylic and Allylic Groups.- 8. Oxidation.- 8.1. Formation of Alcohols.- 8.2. Formation of 1,2 Diols and Amino Alcohols.- 8.3. Acetoxylation.- 8.4. Epoxidation.- 8.4.1. Epoxidation of Allylic Alcohols.- 8.4.2. Asymmetric Epoxidation.- 8.5. Formation of Aldehydes and Ketones.- 8.5.1. Oxidation of Hydrocarbons.- 8.5.2. Oxidation of Alkenes and Alkynes.- 8.5.3. Oxidation of Alcohols.- 8.5.4. Oxidation of Amines.- 8.6. Formation of Acids.- 8.6.1. Oxidation of Alkanes and Alkenes.- 8.6.2. Oxidation of Alcohols.- 8.6.3. Oxidation of Aldehydes and Ketones.- 8.7. Formation of Esters.- 8.8. Dehydrogenation.- 9. Preparing and Handling Transition Metal Catalysts.- 9.1. Introduction.- 9.2. Preparation of Catalysts.- 9.2.1. Chlorotris(triphenylphosphine)rhodium(I)—RhCl(PPh3)3 (Wilkinson’s catalyst).- 9.2.2. trans-Chlorocarbonylbis(triphenylphosphine)-rhodium(I)—trans-RhCl(CO)(PPh3)2.- 9.2.3. Hydridocarbonyltris(triphenylphosphine)—rhodium(I)—RhH(CO)(PPh3)3.- 9.2.4. Dichlorotetrakis(ethylene)dirhodium(I)—[RhCl(C2H4)2]2.- 9.2.5. Dichlorotetracarbonyldirhodium(I)—[RhCl(CO)2]2 (Rhodium Carbonylchloride Dimer).- 9.2.6. cis-Dichlorobis(benzonitrile)palladium(II)—PdCl2(PhCN)2.- 9.2.7. Dichlorobis(triphenylphosphine)palladium(II)—PdCl2(PPh3)2.- 9.2.8. Tetrakis(triphenylphosphine)palladium(0)—Pd(PPh3)4.- 9.2.9. Palladium(II) Acetate Trimer—[Pd(CH3C02)2]3.- 9.2.10. Palladium on Charcoal.- 9.2.11. Lead-Conditioned Palladium on Calcium Carbonate—Selective Hydrogenation Catalyst (Lindlar Catalyst).- 9.2.12. Tetrakis- and Tris(triphenylphosphine)-platinum(0)—Pt(PPh3)4 and Pt(PPh3)3.- 9.2.13. Platinum Oxide Catalyst (Adams’Catalyst).- 9.2.14. Dicyclopentadienylcobalt(II)—Co(C5H5)2 (Cobaltocene).- 9.2.15. Nickel Dichlorobis(phosphine) Complexes—NiCl2(PPh3)2, NiCl2(Ph2PCH2CH2PPh2), and NiCl2(DIOP).- 9.2.16. Bis(l,5-cyclooctadiene)nickel(0)—Ni(C8H12)2.- 9.2.17. trans-Chlorocarbonylbis(triphenylphosphine)-iridium(I)—trans-IrCl(CO)(PPh3)2.- 9.2.18. Dichlorotris(triphenylphosphine)ruthenium(II)—RuCl2(PPh3)3.- 9.3. Metal Acetylacetonates.- 9.4. Arene Metal Tricarbonyls—ArM(CO)3 (M = Cr, Mo, or W).- 9.5. Transition Metal Carbonyls.- 9.6. Recovery of Precious Metals.- 9.7. Handling Air-Sensitive Compounds.- 9.7.1. Reactions under Nitrogen.- 9.7.2. Handling Solids.- 9.7.3. Schlenk-Type Glassware.- References.- Compound Index.