Highly Luminescent Lanthanide Complexes with Specific Coordination Structures
Aus der Reihe
Springer Theses
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Sprache:Englisch
Fr. 138.00
inkl. gesetzl. MwSt.,
Beschreibung
Produktdetails
Einband
Taschenbuch
Erscheinungsdatum
03.09.2016
Abbildungen
XIII, 52 illus., 21 illus. in color., schwarz-weiss Illustrationen, farbige Illustrationen
Verlag
Springer TokyoSeitenzahl
91
Maße (L/B/H)
23.4/15.6/0.6 cm
Gewicht
165 g
Auflage
Softcover reprint of the original 1st ed. 2014
Sprache
Englisch
ISBN
978-4-431-56398-3
This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.
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