Multifunctional Molecular Magnets Based on Octacyanidometalates
Aus der Reihe
Springer Theses
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Sprache:Englisch
Fr. 138.00
inkl. gesetzl. MwSt.,
Beschreibung
Produktdetails
Einband
Gebundene Ausgabe
Erscheinungsdatum
16.08.2017
Abbildungen
XIII, 64 illus., 38 illus. in color., schwarz-weiss Illustrationen, farbige Illustrationen
Verlag
Springer SingaporeSeitenzahl
89
Maße (L/B/H)
24.4/16.1/1.5 cm
Gewicht
313 g
Auflage
1st ed. 2017
Sprache
Englisch
ISBN
978-981-10-6134-9
This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for noveloptical switching devices.
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