• Produktbild: Small-Angle Scattering from Confined and Interfacial Fluids
  • Produktbild: Small-Angle Scattering from Confined and Interfacial Fluids

Small-Angle Scattering from Confined and Interfacial Fluids Applications to Energy Storage and Environmental Science

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Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

23.08.2016

Abbildungen

XIX, 244 illus., 110 illus. in color., farbige Illustrationen, schwarz-weiss Illustrationen

Verlag

Springer

Seitenzahl

314

Maße (L/B/H)

23.5/15.5/1.9 cm

Gewicht

511 g

Auflage

Softcover reprint of the original 1st ed. 2016

Sprache

Englisch

ISBN

978-3-319-34646-5

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

23.08.2016

Abbildungen

XIX, 244 illus., 110 illus. in color., farbige Illustrationen, schwarz-weiss Illustrationen

Verlag

Springer

Seitenzahl

314

Maße (L/B/H)

23.5/15.5/1.9 cm

Gewicht

511 g

Auflage

Softcover reprint of the original 1st ed. 2016

Sprache

Englisch

ISBN

978-3-319-34646-5

Herstelleradresse

Springer-Verlag KG
Sachsenplatz 4-6
1201 Wien
AT

Email: GPSR Kontakt

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  • Produktbild: Small-Angle Scattering from Confined and Interfacial Fluids
  • Produktbild: Small-Angle Scattering from Confined and Interfacial Fluids
  • 1. Basic definitions and essential concepts of small-angle scattering 1.1 Interaction of x-rays and neutrons with matter; scattering length 1.2 Scattering vector and scattering cross section 1.3 Scattering length density and contrast 1.4 Absorption and transmission of x-ray and neutron beams 1.5 Form and structure factors 1.6 Complementarity of neutron and x-ray scattering techniques 2. Radiation sources 2.1 Constant flux reactors 2.2 Spallation neutron sources 2.3 Photon sources 3. Constant flux and time-of-flight instrumentation 3.1 General Purpose SANS instrument at HFIR, ORNL 3.2 Extended Q SANS instrument at SNS, ORNL 3.3 Perfect crystal USANS instrument at NIST 3.4 Time-of-flight USANS at SNS 3.5 SAXS and USAXS instruments at APS, ANL 4. Sample environment 4.1 Sample cells for ambient conditions 4.2 SANS high-pressure cells 4.3 SAXS high-pressure cells 5. Practical aspects of planning and conducting SAS experiments 5.1 Applying for beam time 5.2 Choice of the instrument configuration 5.3 Detector sensitivity and instrument backgrounds 5.4 Optimal sample thickness, transmission and multiple scattering 5.5 Subtraction of the sample background 5.6 Data acquisition time, masking and radial averaging 5.7 Absolute calibration 5.8 Instrument resolution 5.9 Effective thickness of powder samples 5.10 Contrast variation with liquids and gases 5.11 Average scattering length density of multicomponent samples 6. Fundamentals of data analysis 6.1 Correlation functions: mathematical form and geometrical meaning 6.2 Scattering from two-phase random systems: the Porod invariant 6.3 Asymptotic behavior: the Porod law 6.4 Radius of gyration 6.5 Asymptotic behavior: the Guinier approximation 6.6 Structural parameters of the two-phase porous medium 6.7 Bridging the asymptotic behavior: the unified scattering function 6.8 Scattering from fractal systems and the polydisperse spherical model 6.8.1 Scattering from mass, surface, and pore fractals 6.8.2 Polydisperse spherical model 6.9 Beyond the two-phase model 6.9.1 Partial scattering functions of multiphase systems 6.9.2 Scattering contrast and the invariant of a three-phase system 6.9.3 Oscillatory deviations from the Porod law 6.10 Interrelation between the reciprocal and real space 7. Structural characterization of porous materials using SAS 7.1 Porous media for energy, environmental, and biomedical applications 7.2 Porous silica 7.2.1 Porous Vycor glass 7.2.2 Silica aerogels 7.2.3 Porous fractal silica 7.2.4 Ordered mesoporous silica 7.3 Porous carbons 7.3.1 Activated carbons 7.3.2 Glassy carbon 7.3.3 Carbon aerogel 7.4 Alumina membranes 7.5 Porous polymer monoliths 7.6 Ceramics, alloys, and composite materials 7.7 Structure of sedimentary rocks 8. Neutron and x-ray porosimetry 8.1 Principles of the scattering-based porosimetry 8.2 Structure of nanoporous low-dielectric-constant films 8.3 Vapor adsorption in porous silica 8.3.1 Contrast matching SANS 8.3.2 Synchrotron SAXS 8.4 Carbonaceous materials 8.5 Kinetics of sorption and desorption 8.5.1 Dynamic micromapping of CO2 sorption in coal 8.5.2 Vapor adsorption in MCM-41 8.5.3 Vapor and water uptake in Nafion membranes 9. Individual liquids and liquid solutions under confinement 9.1 Confined electrolytes 9.1.1 Ion adsorption in electrolyte saturated porous carbons 9.1.2 Ionic liquids under confinement 9.2 Detection of the oil generation in hydrocarbon source rocks 9.3 Cavitation on hydrophobic nanostructured surfaces 9.4 Liquid-liquid demixing in mesopores 9.5 Supercooled water in confined geometries 9.6 Order-disorder transitions in liquid crystals 10. Supercritical fluids in confined geometries 10.1 Specifics of the supercritical fluid adsorption 10.2 Density fluctuations near the liquid-gas critical point of confined fluids 10.3 Adsorption of supercritical CO2 in porous silica 10.3.1 Silica aerogels 10.3.2 Porous fractal silica 10.4 Methane in porous carbons 10.5 Hydrogen storage in activated carbons 10.6 CO2 sequestration in coal 10.7 Pore interconnectivity and accessibility to fluids in coal and shales 10.8 Structural stability of porous materials under pressure 10.9 Appendix: Derivation of the equation (10.23) for accessible porosity