Foreword xvii
Preface xix
1 Fundamentals of Smart Corrosion Protection Coatings 1
1.1 Introduction of Corrosion Protection Coatings 1
1.1.1 Mechanisms of Corrosion Protection Coatings 2
1.1.2 Failure Type and Failure Mechanism of Corrosion Protection Coatings 3
1.2 Smart Self-healing Coatings 5
1.2.1 Intrinsic Self-healing Coating 5
1.2.1.1 Self-healing Based on Dynamic Bonds 6
1.2.1.2 Self-healing Based on Shape Memory Effect 6
1.2.2 Extrinsic Self-healing Coating 8
1.2.2.1 Self-healing Coating Based on Defect Filling 10
1.2.3 Characterization Methods of Self-healing Properties 14
1.3 Smart Self-reporting Coatings 16
1.4 Superhydrophobic Coatings 17
1.5 Conclusions 20
References 20
2 Development of Thermally Activated Self-healing Coating 29
2.1 Introduction 29
2.2 Thermally Activated Self-healing Coatings to Simultaneously Recover the Corrosion-resistance and Adhesion Strength 29
2.3 Thermally Activated Self-healing Coatings Based on Dual Actions 43
2.4 Chapter Summary 63
References 64
3 Development of Photothermally Activated Self-healing Coating 75
3.1 Introduction 75
3.2 Self-healing Coating Based on GO-CeO 2 Photothermal Fillers 75
3.3 Self-healing Coating Based on TiN-BTA@MSN Photothermal Filler 89
3.4 Self-healing Coating Based on PCL@TiN Photothermal Fillers 109
3.5 Self-healing Coating Based on Fe 3 O 4 -MBT Photothermal Fillers 123
3.6 Chapter Summary 138
References 139
4 Development of pH- and Redox-activated Self-healing Coating 153
4.1 Introduction 153
4.2 pH Responsive Self-healing Coating Based on the Synergistic Effect of Two Corrosion Inhibitors 153
4.3 pH Responsive Self-healing Coating Based on rGO@MS-P-BTA 176
4.4 Redox and Saline Responsive Self-healing Coating Based on PANI/BTA Nanocapsules 188
4.5 Chapter Summary 201
References 203
5 Development of Ion Exchange Activated Self-healing Coating 217
5.1 Introduction 217
5.2 Ion Exchange Activated Self-healing Coating Using GO-LDH Fillers 217
5.3 Chapter Summary 242
References 244
6 Development of pH-responsive and Metal Ion-responsive Self-reporting Coating 251
6.1 Introduction 251
6.2 pH-responsive Self-reporting Coatings Based on PhPh Indicator 252
6.3 Metal Ion-responsive Self-reporting Coatings Based on CDs 253
6.4 Metal Ion-responsive Self-reporting Coatings Based on UF/Phen Microcapsules 279
6.5 Chapter Summary 294
References 296
7 Development of Mechanically Responsive Self-reporting Coating 305
7.1 Introduction 305
7.2 Mechanically Responsive Self-reporting Coating Based on DCF 306
7.3 Chapter Summary 320
References 322
8 Development of Aging-Resistant Coating with Self-healing and Self-reporting Properties 329
8.1 Introduction 329
8.2 Aging-Resistant, Self-healing, and Self-reporting Smart Coatings Based on TA Additives 332
8.3 Aging-Resistant Anticorrosion Coatings Based on TP Additives 369
8.4 Chapter Summary 381
References 383
9 Development of Superhydrophobic Coating with Good Mechanical Durability and Self-healing Effect 393
9.1 Introduction 393
9.2 Preparation and Evaluation of Modified Nano SiO 2 /Epoxy Resin Superhydrophobic Coating 394
9.3 Preparation and Evaluation of CNTs/Epoxy Resin Superhydrophobic Coating 402
9.4 Shape Memory Self-healing Superhydrophobic Coating Based on SiO 2 -CNT Hybrids 413
9.5 Superhydrophobic Self-healing Coating Based on CNTs/LDH Nanocontainers Loaded with Corrosion Inhibitors 424
9.6 Chapter Summary 435
References 437
10 Investigation of the Self-healing Performance of Coatings Using Atmospheric Corrosion Monitor Technique 445
10.1 Introduction 445
10.2 Characterization Methods for Corrosion Protection Coatings 446
10.3 Study of the Self-healing Behavior of Coatings Using ACM Technique 450
10.4 Chapter Summary 475
References 478
11 Future Development Direction of Smart Anticorrosive Coatings 485
11.1 Introduction 485
11.2 Smart Self-healing Coatings 485
11.3 Smart Self-reporting Coatings 490
11.4 Superhydrophobic Coatings 491
11.5 Application of Atmospheric Corrosion Monitor Technology in Smart Coating Design 493
Index 495
