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Produktbild: Boronic Acids

Boronic Acids Preparation and Applications in Organic Synthesis, Medicine and Materials

Fr. 269.00

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Set mit diversen Artikeln

Erscheinungsdatum

19.10.2011

Abbildungen

199 schwarz-weiße Abbildungen, 19 schwarz-weiße Tabellen

Herausgeber

Dennis G. Hall

Verlag

Wiley-VCH

Seitenzahl

726

Maße (L/B/H)

25.1/17.9/4.5 cm

Gewicht

1670 g

Auflage

2. Auflage

Sprache

Englisch

ISBN

978-3-527-32598-6

Beschreibung

Portrait

Dennis Hall obtained his PhD in 1995 from Université de Sherbrooke (Canada), under the direction of Prof. Pierre Deslongchamps. Following
a two-year stay at UC Berkeley as an NSERC Postdoctoral Fellow in the laboratory of Prof. Peter Schultz, he initiated his independent career in 1997 at the University of Alberta (Edmonton, Canada) where he is currently University Professor of Chemistry. The unifying theme of his research program is the development of new applications of organoboronic acid derivatives in organic synthesis, catalysis, and chemical biology. He has co-authored more than 100 publications with over 80 in the fi eld of organoboron chemistry. Recent awards include the 2008
Steacie Prize for Natural Sciences (National Research Council of Canada), and the Royal Society of Canada 2009 Rutherford Memorial
Medal in Chemistry.

Produktdetails

Einband

Set mit diversen Artikeln

Erscheinungsdatum

19.10.2011

Abbildungen

199 schwarz-weiße Abbildungen, 19 schwarz-weiße Tabellen

Herausgeber

Dennis G. Hall

Verlag

Wiley-VCH

Seitenzahl

726

Maße (L/B/H)

25.1/17.9/4.5 cm

Gewicht

1670 g

Auflage

2. Auflage

Sprache

Englisch

ISBN

978-3-527-32598-6

Herstelleradresse

Wiley-VCH GmbH
Boschstr. 12
69469 Weinheim
Deutschland
Email: trade@wiley.com
Url: www.wiley-vch.de
Fax: +49 6201 606328

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  • Produktbild: Boronic Acids
  • VOLUME 1

    Preface

    STRUCTURE, PROPERTIES, AND PREPARATION OF BORONIC ACID DERIVATIVES: OVERVIEW OF THEIR REACTIONS AND APPLICATIONS
    Introduction and Historical Background
    Structure and Properties of Boronic Acid Derivatives
    Preparation of Boronic Acids and Their Esters
    Isolation and Characterization
    Overview of the Reactions of Boronic Acid Derivatives
    Overview of Other Applications of Boronic Acid Derivatives

    METAL-CATALYZED BORYLATION OF C-H AND C-HALOGEN BONDS OF ALKANES, ALKENES, AND ARENES FOR THE SYNTHESIS OF BORONIC ESTERS
    Introduction
    Borylation of Halides and Triflates via Coupling of H-B and B-B Compounds
    Borylation via C-H Activation
    Catalytic Cycle
    Summary

    TRANSITION METAL-CATALYZED ELEMENT-BORYL ADDITIONS TO UNSATURATED ORGANIC COMPOUNDS
    Introduction
    Diboration
    Silaboration
    Carboboration
    Miscellaneous Element-Boryl Additions
    Conclusions

    THE CONTEMPORARY SUZUKI-MIYAURA REACTION
    Introduction
    Developments Made in the Coupling of Nontrivial Substrates
    Asymmetric Suzuki-Miyaura Cross-Couplings
    Iterative Suzuki-Miyaura Cross-Couplings
    Conclusions and Future Outlook

    RHODIUM- AND PALLADIUM-CATALYZED ASYMMETRIC CONJUGATE ADDITIONS OF ORGANOBORONIC ACIDS
    Introduction
    Rh-Catalyzed Enantioselective Conjugate Addition of Organoboron Reagents
    Pd-Catalyzed Enantioselective Conjugate Addition of Organoboron Reagents
    Conclusions

    RECENT ADVANCES IN CHAN-LAM COUPLING REACTION: COPPER-PROMOTED C-HETEROATOM BOND CROSS-COUPLING REACTIONS WITH BORONIC ACIDS AND DERIVATIVES
    General Introduction
    C-O Cross-Coupling with Arylboronic Acids
    C-N Cross-Coupling with Arylboronic Acids
    Substrate Selectivity and Reactivity in Chan-Lam Cross-Coupling Reaction
    C-N and C-O Cross-Coupling with Alkenylboronic Acids
    C-N and C-O Cross-Coupling with Boronic Acid Derivatives
    C-S and C-Se/C-Te Cross-Coupling
    Mechanistic Considerations
    Other Organometalloids
    Conclusion

    VOLUME 2

    TRANSITION METAL-CATALYZED DESULFITATIVE COUPLING OF THIOORGANIC COMPOUNDS WITH BORONIC ACIDS
    General Introduction
    Boronic Acid-Thioorganic C-S Desulfitative Cross-Couplings Using Catalytic Nickel or Palladium
    Thioorganic C-S Desulfitative Cross-Couplings Using Only Catalytic Copper
    Miscellaneous
    Conclusions

    CATALYTIC ADDITIONS OF ALLYLIC BORONATES TO CARBONYL AND IMINE DERIVATIVES
    Introduction
    Additions to Aldehydes
    Additions to Ketones
    Additions to Imine Derivatives
    Conclusions

    RECENT ADVANCES IN NUCLEOPHILIC ADDITION REACTIONS OF ORGANOBORONIC ACIDS AND THEIR DERIVATIVES TO UNSATURATED C-N FUNCTIONALITIES
    Introduction
    Recent Advances in the Petasis Borono-Mannich Reaction
    Reactions of N-Acyliminium Ions with Organoboronic Acids and Their Derivatives
    Advances in Metal-Catalyzed Additions with Organoboronic Acids and Their Derivatives
    Conclusions

    ASYMMETRIC HOMOLOGATION OF BORONIC ESTERS WITH LITHIATED CARBAMATES, EPOXIDES, AND AZIRIDINES
    Introduction
    Lithiated Primary Alkyl Carbamates for the Homologation of Boranes and Boronic Esters
    Lithiated Secondary Carbamates for the Homologation of Boranes and Boronic Esters
    Benzylic N-Linked Lithiated Carbamates for the Homologation of Trialkylboranes
    Lithiated Epoxides for the Homologation of Boronic Esters
    Lithiated Aziridines for the Homologation of Boronic Esters
    Conclusions

    ORGANOTRIFLUOROBORATES: ORGANOBORON REAGENTS FOR THE TWENTY-FIRST CENTURY
    Introduction
    Synthetic Approaches to Organotrifluoroborates
    Elaboration of Organotrifluoroborates via Transformations of Pendant Functional Groups
    Transition Metal-Catalyzed Processes
    Miscellaneous Reactions of Organotrifluoroborates
    Carbon-Carbon Bond-Forming Reactions with Activated Electrophiles
    Conclusions

    BORATE AND BORONIC ACID DERIVATIVES AS CATALYSTS IN ORGANIC SYNTHESIS
    Introduction
    Nonchiral Boron-Based Catalysis
    Chiral Boron-Based Catalysis
    Conclusion

    APPLICATIONS OF BORONIC ACIDS IN CHEMICAL BIOLOGY AND MEDICINAL CHEMISTRY
    Introduction
    Boronic Acids as Potential Medicinal Agents
    Probes for Detecting Reactive Oxygen Species
    MRI and PET Agents for in vivo Carbohydrate Imaging
    Carbohydrate Biomarker Binding Agents and Sensors
    Conclusions

    BORONIC ACIDS IN MATERIALS CHEMISTRY
    Introduction
    Linear Boronate-Linked Materials
    Macrocycles and Cages
    Networks
    Summary and Outlook