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Produktbild: Applied Homogeneous Catalysis

Applied Homogeneous Catalysis

Fr. 209.00

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

14.03.2012

Abbildungen

Tabellen, schwarz-weiss, schwarz-weiss Illustrationen

Verlag

Wiley-VCH

Seitenzahl

716

Maße (L/B/H)

24.7/17.7/3.8 cm

Gewicht

1464 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-3-527-32641-9

Beschreibung

Rezension

"High recommended and excellent value in the paperback format." ( Organic Process Research and Development Journal , 2012)

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

14.03.2012

Abbildungen

Tabellen, schwarz-weiss, schwarz-weiss Illustrationen

Verlag

Wiley-VCH

Seitenzahl

716

Maße (L/B/H)

24.7/17.7/3.8 cm

Gewicht

1464 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-3-527-32641-9

Herstelleradresse

Wiley-VCH GmbH
Boschstr. 12
69469 Weinheim
Deutschland
Email: trade@wiley.com
Url: www.wiley-vch.de
Fax: +49 6201 606328

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  • Produktbild: Applied Homogeneous Catalysis
  • FOREWORD
    PREFACE
    PART I CHEMICAL BASICS
    DEFINITION, OPTIONS, AND EXAMPLES: WHAT ACTUALLY IS CATALYSIS?
    Definition of Catalysis
    The Different Varieties of Catalysis
    The Directing Effect of the Catalyst
    Catalysis as a Part of "Green Chemistry"
    Sources of Information about Catalysis

    A BRIEF HISTORY: HOMOGENEOUS TRANSITION METAL CATALYSIS: A YOUNG SCIENCE
    A Brief History

    INDUSTRIAL HOMOGENEOUS CATALYSIS: WHAT IS THE ECONOMIC IMPORTANCE?
    Application Areas of Catalysis
    Important Homogeneous Catalyzed Processes
    Synthesis of Fine Chemicals by Homogeneous Catalysis

    DEFINITIONS OF IMPORTANT TERMS: SELECTIVITY, STY, TON, TOF, AND MORE. . .
    Conversion
    Yield
    Selectivity
    Other Important Target Values
    The Choice is Yours!

    BONDS, ELEMENTAL STEPS, AND CATALYST CYCLES: BASICS OF ORGANOMETALLIC CHEMISTRY
    Ligands
    Change in Oxidation State
    Changing of Coordination Number (CN) and Coordination Geometry
    The Elementary Steps
    Catalytic Cycles

    TRANSITION METAL COMPLEXES: THE "CAPTAINS" OF HOMOGENEOUS CATALYSIS
    Group IIIB Metals and Lanthanides
    Metals of Group IVB
    Metals of Groups VB to VIIB
    The "Iron Metals" of Group VIII
    The Noble Metals from Group VIII
    Gold: A Noble Metal from Group IB
    The Cost of Catalyst Metals
    The Availability of Transition Metal Catalysts
    A Typical Experiment: Synthesis of Pd(acac)2

    THE COMPLEX LIGANDS: THE "MATES" OF HOMOGENEOUS CATALYSIS
    Monodentate Ligand or Chelate?
    Basicity of Ligands
    Cone Angle ("Tolman Cone Angle")
    The Bite Angle
    Costs and Accessibility of Ligands
    A Typical Experiment: The Synthesis of Biphephos
    Stability of Ligands

    THE SOLVENTS: THE REACTION MEDIUM
    Criteria for Choosing Solvents
    Miscibility of Solvents
    Solvents as Activators
    Solvents as Deactivators
    Availability and Purity of Solvents
    Special Solvents

    ASYMMETRIC CATALYSIS: THE "SPECIAL CASE"
    A Glossary of Asymmetric Catalysis
    A Quick Look Back
    Mechanistic Considerations
    Chiral Ligands
    Overview on Homogeneous Catalyzed Asymmetric Syntheses
    Industrial Applications

    THERMODYNAMICS OF HOMOGENEOUS CATALYSIS: WHEN DOES A CHEMICAL REACTION RUN?
    Gibbs Energy and Energy Plot
    Calculation or Assessment of the Free Reaction Enthalpy
    Thermodynamic Analysis of Complex Reaction Systems

    KINETICS OF HOMOGENEOUS CATALYSIS: HOW DOES THE REACTION PROCEED?
    Frequently Occurring Kinetics
    The Energy Diagram for Explaining Regioselectivity
    The Energy Diagram for Explaining Enantioselectivity
    Execution of Kinetic Measurements
    A Concrete Example: The (Isomerizing) Hydroformylation of Octenes
    Possible Failures in Kinetic Measurements

    OVERVIEW ON SPECTROSCOPIC METHODS: CAN WE SEE INTO HOMOGENEOUS CATALYSIS?
    UV/Visible Spectroscopy
    IR Spectroscopy
    NMR Spectroscopy
    Mass Spectroscopy
    Extended X-Ray Absorption Fine Structure Analysis
    Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES)

    PART II PROCESS ENGINEERING FUNDAMENTALS
    REACTOR TYPES: WHERE DOES CATALYSIS OCCUR?
    Reactions in Homogeneous Liquid Phase
    Fluid-Fluid Systems
    The "Embarras de Richesses"
    Pressure Reactors
    New Trends

    OVERVIEW ON CATALYST RECYCLING METHODS: IS MY CATALYST ECONOMICAL?
    The Principles of Separation
    Precipitation
    Crystallization
    Adsorption

    THERMAL SEPARATION: THE SIMPLEST REMOVAL OF VOLATILE PRODUCTS
    The Basics
    Example: Hydroformylation
    Example: Oxidation of Ethene to Acetaldehyde
    Example: Carbonylation of Methanol to Acetic Acid

    IMMOBILIZATION ON SOLID SUPPORTS: FROM HOMOGENEOUS TO HETEROGENEOUS
    The Basic Principle
    Organic Supports
    Inorganic Supports

    LIQUID-LIQUID MULTIPHASE SYSTEMS: THE SMART APPROACH TO CATALYST SEPARATION
    Variants of Liquid?Liquid Biphasic (LLB) Systems
    Reaction and Separation
    Reactions with In-Situ Extraction
    Reactions with Post Extraction

    THERMOMORPHIC SOLVENT SYSTEMS: CLEVER ENHANCEMENTS
    Thermoregulated Phase-Transfer Catalysis
    Thermoregulated Microemulsions
    Thermoregulated Fluorous Solvent Systems
    Thermoregulated Polymer-Bound Catalysts
    Thermomorphic Multicomponent Solvent Systems
    A Retrospective Look at Catalyst Recycling Methods

    PART III HOMOGENEOUS CATALYZED REACTION TYPES
    AN OVERVIEW OF C?C-BONDING REACTIONS: A GUIDE THROUGH THE JUNGLE

    HYDROFORMYLATIONS: THE INDUSTRIAL ROUTE TO ALDEHYDES AND ALCOHOLS
    Substrates
    Catalysts
    Mechanisms
    Industrial Processes
    Asymmetric Hydroformylation
    A Typical Experiment: Hydroformylation of 1-Octene

    CARBONYLATIONS: THE VERSATILE INSERTIONS OF CARBON MONOXIDE
    Reactions between CO and Hydrogen
    Reactions of CO with Alkenes and Vinyl Arenes
    Reactions of CO with Dienes
    Reactions of CO with Alkynes
    Reactions of CO with Alcohols
    A Typical Experiment

    OLIGOMERIZATION AND CYCLOOLIGOMERIZATION: THE CONVERSION OF UNSATURATED ALIPHATICS INTO SHORT CHAINS OR MEDIUM-SIZED RINGS
    Oligomerization of Alkenes
    Dienes
    Alkynes
    Cooligomerizations
    A Typical Experiment

    METATHESIS: A "CHANGE-YOUR-PARTNERS" DANCE
    Mechanism and Catalysts
    Industrial Applications
    A Typical Experiment: Self Metathesis of 1-Octene

    POLYMERIZATIONS: THE PURPOSEFUL ASSEMBLY OF MACROMOLECULES
    Polyethylene and Ziegler Catalysts
    Polypropylene and Metallocene Catalysis
    Further Polyolefins
    Polydienes
    Polyketones
    Polyalkynes
    Post-Metallocenes
    Current Topics in Polymer Research
    A Typical Experiment

    TELOMERIZATIONS: THE CONSTRUCTION OF C8 AND C10 CHAINS
    Reactions, Mechanisms, and Catalysts
    Butadiene Telomerizations
    Telomerizations with Isoprene
    Telomerizations in Liquid?Liquid Biphasic Systems
    A Typical Experiment

    REACTIONS WITH CARBON DIOXIDE: THE ACTIVATION OF AN "INACTIVE" MOLECULE
    Carbon Dioxide and Alkanes
    Carbon Dioxide and Alkenes
    Carbon Dioxide and Dienes
    Carbon Dioxide and Alkynes
    Carbon Dioxide and Aromatics
    Carbon Dioxide and Hydrogen
    Carbon Dioxide and Epoxides
    Carbon Dioxide and Amines
    Carbon Dioxide-Containing Polymers
    A Typical Experiment

    CARBON-CARBON COUPLING WITH AROMATICS: NEW NAME REACTIONS
    Mizoroki-Heck Reactions
    Sonogashira-Hagihara Reactions
    Suzuki-Miyaura Reaction
    Cross-Couplings with Metal Organyles
    A Typical Experiment

    HYDROGENATIONS: C-H BOND FORMATION
    Catalysts and Mechanisms
    Asymmetric Hydrogenation
    Hydrogenation of Various Functional Groups
    Technical Applications
    A Typical Experiment

    OXIDATIONS: FORMATION OF C-O BONDS
    Wacker Oxidations
    Epoxidations
    Asymmetric Dihydroxylations
    Oxidative Cleavage of C=C Double Bonds
    Oxidations of Alkyl Aromatics
    A Typical Experiment

    AMINATIONS: FORMATION OF C-N BONDS
    Amination of Aryl Halides
    Hydroamination of Alkenes
    Hydroaminations of Dienes
    Hydroamination of Alkynes
    Amination of Functional Groups
    . . .Some More Aminations
    A Typical Experiment

    ISOMERIZATIONS: MIGRATION OF DOUBLE BONDS AND REARRANGEMENT OF THE CARBON BACKBONE
    Isomerization of Alkenes
    Isomerization of Substituted Alkenes
    Rearrangement of the Backbone
    A Typical Experiment

    PART IV NEW TRENDS
    TANDEM REACTIONS: MULTIPLE SYNTHESIS STEPS IN ONE POT
    Multicomponent Reactions
    Multifunctional Catalysis
    Tandem and Related Reactions
    A Typical Experiment

    COMBINATORIAL CHEMISTRY AND HIGH-THROUGHPUT CATALYST SCREENING: THE FAST WAY TO OPTIMUM RESULTS
    Basics and Definitions
    Parallel Reactor Systems
    Sequential Reactor Systems

    GREEN SOLVENTS: WORKING WITH ECO-FRIENDLY SOLVENTS
    Ionic Liquids
    Supercritical Fluids
    Fluorous Solvents
    Polyethers
    Conclusions

    ALKANE ACTIVATIONS: ACQUISITIONS OF NEW FEEDSTOCKS
    Mechanistic Considerations
    Alkane Oxidations
    Alkane Carbonylations
    Alkane Metathesis
    Alkane Hydrogenolysis
    Alkane Borylation
    Alkane Sulfonation
    A Look Back

    MORE EFFICIENT LIGANDS: THE BEST IS THE ENEMY OF THE GOOD
    Nitrogen-Containing Ligands
    Unusual Phosphorus Ligands
    Ligands Containing Elements from Group VIA
    Ligands Containing Elements from Group IVA

    NANOCATALYSIS: BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS
    Synthesis and Properties of Nanocatalysts
    Stabilization of Nanoparticles
    Heterogenization of Nanoparticles on Solid Supports
    Catalysis Involving Metal Nanoparticles

    HOMOGENEOUS CATALYSIS WITH RENEWABLES: USING NATURE.S TREASURES
    Catalytic Conversion of Fatty Compounds
    Catalytic Reactions of Carbohydrates
    Catalytic Reactions of Terpenes

    ELECTROCATALYSIS/SONOCATALYSIS/PHOTOCATALYSIS/MICROWAVE/EXTREME PRESSURE: ALTERNATIVE METHODS OF ACTIVATION
    Electrocatalysis
    Photocatalysis
    Sonocatalysis
    Microwave Catalysis
    Extreme High-Pressure Catalysis

    PROCESS DEVELOPMENT IN MINIPLANTS: FROM LABORATORY TO PRODUCTION
    Miniplant with Continuously Stirred-Tank Reactor (Miniplant I)
    Miniplant with Loop Reactor and Phase Separator (Miniplant II)
    Miniplant with Jetloop Reactor and Phase Separator (Miniplant III)
    Miniplant with a Mixer?Settler Battery (Miniplant IV)

    THE FUTURE OF HOMOGENEOUS CATALYSIS: A LOOK AHEAD
    New Resources
    New Reactions
    New Catalysts
    New Methods

    ANSWERS TO THE QUICKIES