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Produktbild: Efficient Preparations of Fluorine Compounds

Efficient Preparations of Fluorine Compounds

Fr. 199.00

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

06.11.2012

Herausgeber

Herbert W. Roesky

Verlag

John Wiley & Sons Inc

Seitenzahl

480

Maße (L/B/H)

24/16.1/3 cm

Gewicht

888 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-1-118-07856-3

Beschreibung

Rezension

"As Prof. K. Barry Sharpless comments in the Foreword, 'Many years of experience, together with deep and catholic knowledge of chemical reactivity principles, is the important coin in this [fluorine chemistry] realm', and I would recommend this book to anyone involved in synthetic chemistry interested in laboratory synthesis involving fluorinating reagents or fluorinated molecules as an introduction into the experimental and chemical reactivity possibilities now available." ( ChemMedChem , 1 August 2013)

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

06.11.2012

Herausgeber

Herbert W. Roesky

Verlag

John Wiley & Sons Inc

Seitenzahl

480

Maße (L/B/H)

24/16.1/3 cm

Gewicht

888 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-1-118-07856-3

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: GPSR Kontakt

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  • Produktbild: Efficient Preparations of Fluorine Compounds
  • Foreword xi

    Preface xiii

    Contributors xv

    1 Preparation of Elemental Fluorine 1
    Karl O. Christe

    2 Preparation of Highly Active Cesium Fluoride 7
    Konrad Seppelt

    3 Preparation of Highly Active Silver Fluoride 9
    Konrad Seppelt

    4 A Room-Temperature Non-Irradiative Synthesis of XeF2 11
    Ulf Breddemann, John R. DeBackere, and Gary J. Schrobilgen

    5 Efficient Perfluorination of K2B12H12 in Neutral Acetonitrile 16
    Dmitry V. Peryshkov, Eric V. Bukovsky, and Steven H. Strauss

    6 Efficient Preparation of the Highly Soluble ortho- and para-C60(CF2C6F5)2 Derivatives 19
    Igor V. Kuvychko, Bryon W. Larson, Steven H. Strauss, and Olga V. Boltalina

    7 Synthesis of Cs[1-H-CB11F11] 22
    Michal Vala¡sek, Filip Šembera, Michael J. Hughes, Ivan Stibor, Zbyn¡ek Janou¡sek, and Josef Michl

    8 Synthesis of Zero-Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te), and Related Compounds 26
    Wieland Tyrra and Silke Kremer

    9 Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications 35
    Dayal T. Meshri, N. C. Mathur, and Ritesh R. Jain

    10 Tris(pentafluorophenyl)borane, B(C6F5)3, a Powerful, Well-Soluble, Nonoxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4]¿ 60
    Hermann-Josef Frohn

    11 Pentafluorophenyldifluoroborane, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Nonmetal Fluorides 65
    Hermann-Josef Frohn

    12 Iodine(III and V) Fluorides: Interesting Fluorinating Agents 72
    Hermann-Josef Frohn

    13 Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles 76
    Hermann-Josef Frohn

    14 Preparation of Transition Metal Sulfide Fluorides 79
    Michael Gerken

    15 Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand 82
    Rudiger Mews

    16 Cesium, Mercury, and Silver Salts with Sulfur-Nitrogen-Fluorine Anions: Useful Transfer Reagents for NSF Building Blocks 88
    Rudiger Mews

    17 Laboratory-Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride 94
    Thomas M. Klapotke

    18 Preparation of Transition Metal Fluorides using ClF3 100
    Ralf Haiges

    19 Preparation of Fluorine-Containing Molecular Halides and Heteropolar Salts with Elements of Group 15 and Niobium and Tantalum Halides 108
    Lothar Kolditz

    20 Fluoro and Fluorohydroxy Complexes of As, Sb, and Sn 117
    Lothar Kolditz

    21 Trifluoromethyl Compounds via Electrophilic and Nucleophilic Reactions 121
    Jeanne M. Shreeve

    22 Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions 127
    Jeanne M. Shreeve

    23 The "Real" Iodine and Bromine Monofluorides 133
    Shlomo Rozen

    24 The Versatile Chemistry of Acetyl Hypofluorite: The First Hypofluorite Not Bonded to a Polyhaloalkyl Group 139
    Shlomo Rozen

    25 Direct Fluorination of Organic Compounds with Elemental Fluorine 146
    Shlomo Rozen

    26 The Surprising Chemistry of Bromine Trifluoride 154
    Shlomo Rozen

    27 Preparation of Silicon- and Sulfur-Based Fluorinated Methane Derivatives as Versatile Fluoromethylation Reagents 173
    G.K. Surya Prakash and Fang Wang

    28 Pentafluoroethyl Lithium: Reactions with Carbonyl Compounds and Epoxides 205
    Olesya Kazakova and Gerd-Volker Roschenthaler

    29 Synthesis of gamma-Hydroxy-gamma, gamma-difluoromethylenephosphonates 210
    Olesya Kazakova and Gerd-Volker Roschenthaler

    30 Synthesis of Pentafluoro-gamma6-sulfanyl-Substituted Acetylenes for Liquid Crystals 214
    Olesya Kazakova, Maxim Ponomarenko, and Gerd-Volker Roschenthaler

    31 Delocalized Lipophilic Cations as a Source of Naked Fluoride and Phase-Transfer Catalysts 220
    Nataliya Kalinovich, Olesya Kazakova, and Gerd-Volker Roschenthaler

    32 Methyltrifluoropyruvate Imines Possessing N-oxalyl and N-Phosphonoformyl Groups: Precursors to a Variety of Alpha-CF3-Alpha-Amino Acid Derivatives 227
    Olesya Kazakova and Gerd-Volker Roschenthaler

    33 Rhodium-Mediated Synthesis of (3,3,3-Trifluoropropyl)trimethoxysilane and (3,3,3-Trifluoropropyl)triphenylsilane 232
    Falk Wehmeier and Thomas Braun

    34 Rhodium-Mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester 235
    Michael Teltewskoi and Thomas Braun

    35 Palladium-Mediated Synthesis of 4-Vinyltetrafluoropyridine and 2,3,5,6-Tetrafluoropyridine 237
    David Breyer and Thomas Braun

    36 Preparation of Polyfluoroaryl-1,2-difluorovinylsilanes 240
    Donald J. Burton and Ba V. Nguyen

    37 Preparation of (Z)-2-iodo-1,2-difluorostyrenes 243
    Donald J. Burton and Ling Xue

    38 Preparation of 1,4-Bis(Z-2-iodo-1,2-difluoroethenyl)benzene 246
    Donald J. Burton and Craig A. Wesolowski

    39 Stereospecific Carboamidation Route to (Z)-N-Phenyl-2,3-difluoro-3-(triethylsilyl) acrylamide 248
    Donald J. Burton and Craig A. Wesolowski

    40 Preparation of 2-Trifluoromethyl-3,3,3-trifluoropropanal 250
    Donald J. Burton and Donald A. Wiebe

    41 Synthesis of Tetrafluorocatechol 252
    Sudharsanam Ramanathan, Dayong Sang, Vivek Kumar, and David M. Lemal

    42 Preparation of an Unsymmetrical Bis((perfluoroalkyl)sulfonyl)imide 256
    Darryl D. Desmarteau and Thomas D. Hickman

    43 Preparation of Perfluoroalkyl Sulfilimines and Sulfoximines 262
    Emmanuel Magnier

    44 Preparation of Trifluoromethylsulfonium Salts 266
    Emmanuel Magnier

    45 Preparation of Organometallic Fluorides of Main Group and Transition Elements 270
    Herbert W. Roesky

    46 Preparation of Pentafluorosulfanyl Carbonyl Compounds 275
    John T. Welch

    47 Preparation of Power-Variable Electrophilic Trifluoromethylating Agents, S-(Trifluoromethyl)dibenzothiophenium Salts Series 279
    Teruo Umemoto

    48 Synthesis of Fluorine-Containing Heterocycles from alpha,alpha-Dihydropolyfluoroalkylsulfides and Fluorinated Thiocarboxylic Acids Derivatives 290
    Vadim M. Timoshemko and Yuriy G. Shermolovich

    49 Synthesis of Octafluorocyclooctatetraene 308
    John M. Buzby, Aldos C. Barefoot, III, Michael W. Grayston, Evan D. Laganis, Roy F. Waldron, and David M. Lemal

    50 Preparation of Fluoroolefins 315
    Moritz F. Kuhnel and Dieter Lentz

    51 Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid-Base Reactions 334
    Kazuhiko Matsumoto and Rika Hagiwara

    52 Synthesis of Difluorocyclopropyl Building Blocks: 2,2-Difluorocyclopropylmethanol and 2-(Bromomethyl)-1,1-difluorocyclopropane 338
    Wei Xu and William R. Dolbier Jr.

    53 Preparation of 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane and Perfluoro[2.2]paracyclophane 343
    William R. Dolbier Jr., Jian-Xi Duan, Alex J. Roche, and Lianhao Zhang

    54 Synthesis and Application of gem-Difluoromethylenated and Trifluoromethylated Building Blocks 349
    Feng-Ling Qing and Xiao-Long Qiu

    55 1,3-Dipolar Cycloaddition Reactions to Fluoroalkenes 365
    Hanna Wojtowicz-Rajchel and Henryk Koroniak

    56 Synthesis of Fluorinated Vinyl Derivatives of Nucleic Acid Bases 370
    Hanna Wojtowicz-Rajchel, Donata Pluskota-Karwatka, and Henryk Koroniak

    57 Synthesis of CF3-Substituted Aziridine Ring by the Gabriel Reaction 375
    Tomasz Cytlak, Bartosz Marciniak, and Henryk Koroniak

    58 Preparation of alpha-Fluoro Amino and alpha-Fluoro Enamino Reagents 379
    Justyna Walkowiak and Henryk Koroniak

    59 Synthesis of Original Fluoromonomers and Their Radical Copolymerization with Vinylidene Fluoride 385
    Bruno Ameduri

    60 Convergent 18F Radiosynthesis 396
    V. Gouverneur and O. Lozano

    61 Asymmetric Fluorocyclization Reactions 400
    V. Gouverneur and O. Lozano

    62 Preparation of Allylic Fluorides 405
    V. Gouverneur and O. Lozano

    63 Dehydroxyfluorinations of Primary or Secondary Alcohols Using Perfluoro n-Butylsulfonyl Fluoride (Nonaflyl Fluoride) in Combination with 1,8-Diaza-bicyclo[5.4.0]undec-7-ene 412
    Orlin Petrov, Matthias Schneider, Rolf Bohlmann, Stephan Vettel, and Helmut Vorbr¿uggen

    64 Preparation of Rare Earth Fluorosulfides and Oxyfluorosulfides 415
    A. Demourgues and A. Tressaud

    65 Preparation of Carbon-Fluorine Compounds and Fluoride or Oxide Fluoride-Intercalated Graphites 425
    Tsuyoshi Nakajima

    66 Safe Synthesis of Superstoichiometric Mesoporous Fluorocarbons 433
    Valentin N. Mitkin

    67 Preparation of Fluorinated alpha-Alumina 442
    Erhard Kemnitz, Toma¡z Skapin, and John M. Winfield

    68 High-Yield Synthesis of a Single Asymmetric Isomer of C70(CF3)10 by High-Temperature Radical Trifluoromethylation 447
    Natalia B. Shustova, Steven H. Strauss, and Olga V. Boltalina

    Index 451