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Produktbild: Olefin Metathesis and Metathesis Polymerization

Olefin Metathesis and Metathesis Polymerization

Fr. 222.00

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

22.01.1997

Verlag

Elsevier Science & Technology

Seitenzahl

496

Maße (L/B/H)

23.6/15.6/3 cm

Gewicht

871 g

Auflage

2nd Revised edition

Sprache

Englisch

ISBN

978-0-12-377045-5

Beschreibung

Rezension

"Coverage of the literature is up-to-date...,and the book is very well indexed; there is no difficulty in finding your way to a topic of interest. As a document of an important branch of organometallic chemistry, this book is complete and should satisfy all chemists with an interest in olefin metathesis and related reactions." --JOURNAL OF AMERICAN CHEMISTRY SOCIETY

"Any reader wishing to know anything about olefin matathesis and metathesis polymerization cannot do better than start with this excellant monograph. . . Nobody active in the area can afford to be without this monograph and any library which serves a research community interest in catalysis, organic synthesis and polymer science and technology will need this book on its shelves." --POLYMER INTERNATIONAL, Vol. 45, 1998

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

22.01.1997

Verlag

Elsevier Science & Technology

Seitenzahl

496

Maße (L/B/H)

23.6/15.6/3 cm

Gewicht

871 g

Auflage

2nd Revised edition

Sprache

Englisch

ISBN

978-0-12-377045-5

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Zeitfracht Medien GmbH
Ferdinand-Jühlke-Straße 7|99095|Erfurt|DE
produktsicherheit@zeitfracht.de

Herstelleradresse

Elsevier Science & Technology
125 London Wall|EC2Y 5AS|London|GB
tradeorders@elsevier.com

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  • Produktbild: Olefin Metathesis and Metathesis Polymerization
  • Preface. Abbreviations. Introduction: The Olefin Metathesis Reaction. Brief History. The Metal Carbene Mechanism. Equilibria and Stereoselectivity. Survey of Catalyst Systems: Group IV. Group V. GroupVI. Group VII. Group VIII. Photochemically Activated Catalysts. The Metal Carbene/Metallacyclobutane Mechanism: Evidence from Cross-Metathesis Reactions. Evidence from the Stereochemistry of Metathesis of Internal Olefins. Evidence from Ring-Opening Metathesis Polymerization (ROMP). Evidence from the reactions of Well-Defined Metal Carbene Complexes. Evidence from the Reactions of Metallacyclobutane Complexes. Evidence of Initiating Species in Systems with Non-Carbene Catalysts. Theoretical Treatments. Related Reactions: [2+2] Reactions Between Compounds Containing Multiple Bonds. Relationship to Ziegler-Natta Polymerization. Involvement of Three-Membered Ring Compounds in Metathesis Reactions. Ethene and Terminal Alkenes: Ethene. Propene. But-1-ene and its Derivatives. Pent-1-ene and its Derivatives. Hex-1-ene and its Derivatives. Higher Acyclic Terminal Alkenes. Acyclic Disubstituted and Trisubstituted Ethenes. Cis/trans Isomerization. Pent-2-ene and 4-Substituted Derivatives. Hex-2-ene and 4-Methylhex-2-ene.Hept-2-ene and Hept-3-ene. Higher Acyclic Internal Olefins. Stereoselectivity in the Metathesis of Acyclic Olefins. 1,1-Disubstituted Olefins. Trisubstituted Ethenes. Acyclic Functionalized Alkenes: Esters. Other Carbonyl-Containing Compounds. Ethers. Amines. Nitriles. Chlorides and Bromides. Sulfides and Sulfonates. Silancs and Germanes. Phospanes. Acyclic Dienes: Double Bonds Linked only by C Atoms. Double Bonds Linked by C and Si, Ge orSn Atoms. Double Bonds Linked by C and N Atoms. Double Bonds Linked by C, Si, and O Atoms. Divinylferrocene. Some Further Applications in Organic Synthesis. Copolymers by Metathesis Condensation. Cross-Metathesis Between Acyclic Compounds: Ethene.Propene. Butenes. Pentenes. Hexenes. Higher Olefins. Functionalized Olefins. Acetylenes: Metathesis Reactions Involving Total Cleavage of the C=C bond. Metathesis Reactions Involving Cleavage of Two of the thress C=C Bonds. Metathesis Reactions of Enynes and Dienynes. Other Metathesis Routes to Polyacetylenes. Ring-Opening Metathesis Polymerization: General Aspects: Thermodynamic Aspects. Efficiency of Initiation. The Use of Chain-Transfer Agents. Molecular Weight Distributions. Polymer Micostructure. Monocyclic Alkenes and Polyenes: Four-Membered Rings. Five-Membered Rings. Six-Membered Rings. Seven-Membered Rings. Eight-Membered Rings. Nine-Membered Rings. Ten-Membered Rings. Twelve-Membered and Other Rings. Polycyclic Alkenes: Monomers Containing a Fused Cyclobutene Ring. Monomers Containing a Fused Cyclopentene Ring and One Double Bond. Monomers Containing a Fused Cyclopentene Ring and More than One Double Bond. Bicyclo[2.2.1] Compounds Containing Heteroatoms in the Ring System. Other Bicyclic Compounds. Copolymers of Cycloalkenes: Direct Metathesis Copolymerization. Cyclic Co-Oligomers. Block Copolymers by Sequential Addition of Monomers to Living Systems. Block Copolymers by Modification of Homopolymers. Comb and GraftCopolymers. Copolymers by ROMP in Conjunction with Radical Reactions. Cross-Metathesis Between Cyclic and Acyclic Olefins: End-Groups and Telomers. Dependence of Molecular Weight on [M2]/[M1]. Kinetic Data. Degradation of UnsaturatedPolymers by Metathesis: Degradation by Intramolecular Metathesis. Applications of the Olefin Metathesis Reaction: The Phillips Triolefin Process. The Neohexene Process. The Shell Higher Olefins Process. Other Multistage Processes Involving Metathesis. The Isoamylene Process. ( Circle around alpha and omega) ((-Diolefins. trans-Poly(1-Pentenylene). trans-Poly(1-octenylene). Polymers of Norhornene. Polymers of Norbornene Derivatives. Miscellaneous. Bibliography. Subject Index.