Geschäftskunden Kundenprogramme
Vor Ort
Merkzettel Warenkorb
Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products
Band 31

Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products

Aus der Reihe

Fr. 72.90

inkl. gesetzl. MwSt.
Versandkostenfrei
Taschenbuch

Taschenbuch

Fr. 72.90 eBook

eBook

Fr. 62.90

Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products

Ebenfalls verfügbar als:

Taschenbuch

Taschenbuch

ab Fr. 72.90
eBook

eBook

ab Fr. 62.90

Beschreibung

Details

Einband

Taschenbuch

Erscheinungsdatum

06.11.2011

Verlag

Springer Wien

Seitenzahl

696

Maße (L/B/H)

23.5/15.5/3.8 cm

Beschreibung

Details

Einband

Taschenbuch

Erscheinungsdatum

06.11.2011

Verlag

Springer Wien

Seitenzahl

696

Maße (L/B/H)

23.5/15.5/3.8 cm

Gewicht

1060 g

Auflage

Softcover reprint of the original 1st ed. 1974

Sprache

Deutsch, Englisch

ISBN

978-3-7091-7096-0

Weitere Bände von Fortschritte der Chemie organischer Naturstoffe Progress in the Chemistry of Organic Natural Products

Unsere Kundinnen und Kunden meinen

0.0

0 Bewertungen

Informationen zu Bewertungen

Zur Abgabe einer Bewertung ist eine Anmeldung im Konto notwendig. Die Authentizität der Bewertungen wird von uns nicht überprüft. Wir behalten uns vor, Bewertungstexte, die unseren Richtlinien widersprechen, entsprechend zu kürzen oder zu löschen.

Verfassen Sie die erste Bewertung zu diesem Artikel

Helfen Sie anderen Kund*innen durch Ihre Meinung

Erste Bewertung verfassen

Unsere Kundinnen und Kunden meinen

0.0

0 Bewertungen filtern

Weitere Artikel finden Sie in
  • Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products
  • / Contents.- Recent Developments in the Chemistry of Penicillins.- I. Introduction.- II. Nomenclature.- III. Reactions at the ?-Lactam Ring.- A. Acylation of the 6-Amino Group.- B. Alkylation of the 6-Amino Group.- C. Hydrolysis of the 6-Amido Group.- D. Epimerization at the 6-Position.- E. Diazotization of the 6-Amino Group.- F. Substitution at the 6-Position.- G. Cleavage of the C-7-N-4 Bond.- IV. Reactions at the Thiazolidine Ring.- A. Rearrangements of Penicillin Sulfoxides.- B. Other Thiazolidine Ring Cleavages.- C. Miscellaneous Nuclear Transformations.- D. Modification of the 3-Carboxylic Acid.- V. Conclusion.- References.- The Antibiotic Complex of the Verrucarins and Roridins.- I. Introduction.- II. Production and Isolation.- III. Structure and Chemical Transformations.- 1. Sterols.- 2. Chromane Derivatives.- 2.1. Myrochromanol and Myrochromanone.- 3. Pyrrole Derivatives.- 3.1. Verrucarin E.- 3.2. Verrucarin G.- 4. Macrocyclic Trichothecane Esters.- 4.1. Verrucarol and Roridin C (Trichodermol).- 4.2. Verrucarin A and 2?-Dehydroverrucarin A.- 4.3. Verrucarin B.- 4.4. Verrucarin J.- 4.5. Roridin A.- 4.6. Roridin D.- 4.7. Roridin E.- 4.8. Roridin H.- 5. Wortmannin.- IV. Total Synthesis.- V. Methods of Assay.- VI. Biosynthesis.- 1. Pyrrole Derivatives.- 2. Trichothecane Esters.- VII. Biological Activity.- 1. Antibiotic Activity.- 2. Cytostatic Activity.- 3. Toxicity.- 4. Structure and Biological Activity.- Acknowledgement.- References.- Aflatoxins and Sterigmatocystins.- I. Introduction.- II. Isolation and Characterisation of the Mycotoxins.- III. Structural Elucidation of the Mycotoxins.- 1. Sterigmatocystin.- 2. Other Metabolites Closely Related to Sterigmatocystin.- 3. Aspertoxin.- 4. Aflatoxin-B1, -B2, -Gl, and -G2.- 5. Aflatoxin-M1 and -M2.- 6. Aflatoxin-B2a and -G2a.- IV. Synthesis of the (±)-Forms of the Mycotoxins and of Related Compounds.- 1. Tetrahydro-4-hydroxy-6-methoxyfuro[2,3-b]benzofuran.- 2. Tetrahydrodeoxoaflatoxin-B1.- 3. Aflatoxin-B1.- 4. Aflatoxin-B2.- 5. Aflatoxin-G1.- 6. Aflatoxin-M1.- 7. Dihydro-O-methylsterigmatocystin.- 8. O-methylsterigmatocystin.- V. Biogenesis of the Mycotoxins.- 1. Sterigmatocystin.- 2. Aflatoxin-B1.- VI. Conclusion.- References.- Flavonoid-Glykoside.- I. Strukturtypen von Flavonoid-O-Glykosiden und ihre Verbreitung.- 1. Glykosidierungsmuster.- 2. O-Monoside.- 3. O-Bioside.- 4. O-Trioside, Tri-, Tetra- und Poly-O-Glykoside.- 5.O-Glykuronide.- 6. Acyl-O-Glykoside.- II. Flavonoid-C-Glykoside.- III. Synthese von Flavonoidglykosiden.- 1. Darstellung von Acetobromzuckern.- 2. Synthese von O-Monosiden und O-Biosiden.- a) Glykosidierung der C7-OH-Gruppe.- b) Glykosidierung der C3-OH-Gruppe.- c) Glykosidierung der C4?-C2?-C3?-C5-OH-Gruppen.- 3. Synthese von Flavonoid-O-Bisglykosiden.- 4. Synthese von Flavonoid-C-Glykosiden.- Addenda.- Biogenetic-Type Syntheses of Polyketide Metabolites.- I. Introduction.- II. Early Studies.- III. Modern Concepts of Polyketide Biosynthesis.- IV. Experimental Support for the Polyketide Theory.- V. Syntheses of ?-Polycarbonyl Compounds.- 1. 3,5-Diketo Acids and Esters.- 2. 1,3,5-Triketones.- 3. 3,5,7-Triketo Acids and Esters.- 4. 1,3,5,7-Tetraketones.- 5. 3,5,7,9-Tetraketo Acids and Esters.- 6. 1,3,5,7,9-Pentaketones.- 7. 3,5,7,9,11-Pentaketo Acids and Esters.- 8. 1,3,5,7,9,11-Hexaketones.- 9. ?-Heptacarbonyl Compounds.- 10. ?-Octacarbonyl Compounds.- 11. ?-Nonacarbonyl Compounds.- 12. Reduced Polycarbonyl Compounds.- VI. Cyclizations of ?-Polycarbonyl Compounds.- 1. Using Several Ketide Fragments.- 2. Using a Single Polycarbonyl Compound.- a) With 3,5-Diketo Acids.- b) With 1,3,5-Triketones.- c) With 3,5,7-Triketo Acids and Esters.- d) With 1,3,5,7-Tetraketones.- e) With 3,5,7,9-Tetraketo Acids and Esters.- f) With 1,3,5,7,9-Pentaketones.- g) With ?-Hexacarbonyl Compounds.- h) With ?-Heptacarbonyl Compounds.- i) With ?-Octacarbonyl Compounds.- j) With ?-Nonacarbonyl Compounds.- k) With Reduced ?-Polycarbonyl Compounds.- 3. Using Partially Cyclized Polycarbonyl Compounds.- VII. Conclusions.- References.- The Chemistry of Spiro[4.5]Decane Sesquiterpenes.- A. Introduction.- B. The Acoranes and Alaskanes.- 1. Structure Elucidation of the Acorus Spiranes.- 2. The Alaskanes, Precursors of Cedrene.- 3. Mass Spectral Considerations.- 4. Synthesis.- C. The Spirovetivanes.- 1. Structure.- a) Agarospirol.- b) ?-Vetivone and Related Compounds.- 2. Synthesis.- D. Biogenetic Considerations.- 1. The Relationship between Spirovetivanes and Hydronaphthalenic Sesquiterpenes.- 2. Alaskane-Acorane Spiranes as Precursors of Tricyclic Sesquiterpenes.- 3. Chemical Simulation of Biogenetic Pathways involving Spiro[4.5]Decanes.- E. Tables of Naturally Occurring Spiro[4.5]Decanes.- Addendum.- References.- Phorbolesters — the Irritants and Cocarcinogens of Croton Tiglium L..- 1. Introduction.- 2. Fractionation of Croton Oil.- 2.1. General Analytical Chemical Procedures and Biological Assays.- 2.1.1. Methods of Separation and Criteria of Purity.- 2.1.2. Monitoring of Fractionation Steps.- 2.2. Preparation of the Hydrophilic and the Hydrophobic Portions.- 2.3. Phorbol Diesters from the Hydrophilic Portion.- 2.3.1. Isolation and Resolution of Croton Oil Factor Groups A and B.- 2.3.2. Chemical Characterization of the Croton Oil Factors from Groups A and B as Diesters of Phorbol.- 2.4. Higher Phorbol Esters from the Hydrophobic Portion.- 2.4.1. Isolation and Resolution of Croton Oil Factor Groups A’ and B’.- 2.4.2. Separation and Chemical Characterization of the Croton Oil Factors from Groups A’ and B’.- 3. Chemistry of Phorbol and of the Croton Oil Factors.- 3.1. Structure and Stereochemistry of Phorbol.- 3.2. Reactions Altering the Functional Groups of Phorbol.- 3.2.1. Functional Derivatives of the Carbonyl Group.- Reaction with Carbonyl Reagents.- Reduction of the Carbonyl Group.- 3.2.2. Functional Derivatives of the Hydroxyl Groups.- Phorbol Esters.- Phorbol Ethers.- Oxidation of Single Hydroxyl Groups.- Substitution and Elimination of Hydroxyl Groups.- 3.2.3. Functional Derivatives Involving the C = C-Bonds.- Catalytic Hydrogenation.- Bromination and Hydrobromination.- Oxidation.- 3.3. Structure of the Croton Oil Factors.- 3.3.1. Phorbol Diesters from the Hydrophilic Portion.- 3.3.2. Phorbol Triesters from the Hydrophobic Portion.- 3.4. Reactions Altering the Tigliane Skeleton of Phorbol and of Neophorbol.- 3.4.1. Dehydrogenation of Phorbol and 3-Deoxo-3?-hydroxyphorbol.- 3.4.2. Oxidative Ring Opening of Phorbol and Derivatives.- Ring A.- Ring B.- Rings C and D (Bicyclo[4.1.0]heptane System).- 3.4.3. Rearrangements in Phorbol and Neophorbol involving the Bicyclo[4.1.0]-heptane System.- Crotophorbolone-enol-13,20-diacetate and Acetoxycrotophorbolone-20-acetate.- Phorbobutanone and Phorboisobutanone.- The “Flaschenträger Reaction”.- 12,13-Ketol Rearrangement in Neophorbol.- 4. Further Diterpenes and Diterpene Esters from Croton Oil.- 4.1. Chemistry of 4?-Phorbol.- 4.2. Chemistry of 4-Deoxy-4?-phorbol and 4-Deoxyphorbol.- 4.3. Compound Groups D, E, D’ and E’ from Croton Oil.- 4.4. Composition of Croton Oil with Regard to Diterpenes and their Esters.- 5. On the Biological Activities of the Isolated Diterpenes and their Esters.- 6. Conclusions and Perspectives.- References.- Stereoselektive Totalsynthese von Indolalkaloiden..- Structure, Chemistry, and Biosynthesis of the Melanins..- I. Introduction.- II. Enzymic Nature of Melanogenesis.- 1. Melanogenesis in Invertebrates and Plants.- 2. Melanogenesis in Vertebrates.- 3. The Enzyme.- III. Allomelanins.- 1. Catechol-Melanin.- 2. Natural Allomelanins.- IV. Eumelanins.- 1. Chemical Investigations on Dopa-Melanin and 5,6-Dihydroxyindole-Melanin.- 1.1. Introduction.- 1.2. Studies on Model Compounds.- 1.3. Isotopic and Degradative Studies.- 1.4. Conclusion Regarding the Structure of Melanin.- 1.5. Studies Relevant to the Structure of the Melanoproteins.- 2. Chemical and Biochemical Investigations on Natural Eumelanins.- 2.1. Introduction.- 2.2. Sepiomelanin.- 2.3. Melanin from Melanoma.- 2.4. Melanin from Hair.- 2.5. Melanin from the Eye.- 2.6. Other Melanins.- 3. Investigations on Melanins by Spectroscopic and other Physical Methods.- 3.1. Ultraviolet and Infrared Spectra.- 3.2. X-Ray Diffraction.- 3.3. Electron Spin Resonance.- 4. Adrenochrome-Melanin.- 5. Dopamine-Melanin.- V. Phaeomelanins.- VI. Conclusions.- References.- Addendum.- Mechanisms of Corrin Dependent Enzymatic Reactions..- I. Introduction.- II. Nomenclature.- III. Properties and Reactions of Corrins and Related Compounds.- 1. Vitamin B12 Chemistry.- 2. Vitamin B12 Model Compounds.- 3. Coenzyme B12 Reactions.- IV. Coenzyme B12 Dependent Enzymatic Reactions.- 1. Dioldehydrases.- 2. Ethanolamine Deaminase.- 3. Ribonucleotide Reductase.- 4. Mutases.- 5. Aminomutases.- V. Corrin Dependent Enzymatic Reactions.- 1. Methane Biosynthesis.- 2. Acetate Biosynthesis.- 3. Methylarsine Biosynthesis.- 4. Methylmercury Formation.- 5. Methionine Biosynthesis.- References.- Namenverzeichnis. Author Index.- Sachverzeichnis. Subject Index.