P Phosphorus Mononuclear Compounds with Hydrogen
Aus der Reihe
P. Phosphor. Phosphorus (System-Nr. 16)
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Sprache:Englisch
Fr. 73.90
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Beschreibung
Produktdetails
Einband
Taschenbuch
Erscheinungsdatum
03.10.2013
Abbildungen
XVI, 1 illus., schwarz-weiss Illustrationen
Herausgeber
Werner Behrendt + weitereVerlag
Springer BerlinSeitenzahl
326
Maße (L/B/H)
25.9/17.7/2.2 cm
Gewicht
662 g
Auflage
Eighth Edition 1993
Sprache
Englisch
ISBN
978-3-662-08849-4
This volume C 1 is the first supplement volume to "Phosphor" C which was published in 1965 and covers the compounds of phosphorus. Starting with the binary species formed between phosphorus and hydrogen, the present volume deals with the neutral mononuclear compounds PH through PH ; the ions featuring the same stoichiometric composition are s covered in separate sections. PH and PH are the major initial gaseous decomposition products of PH and, thus, also 2 J intermediates in many of its gas-phase reactions. Both molecules and their ions have been thoroughly investigated by a variety of modern, high-resolution spectroscopic methods during the last three decades. The coverage of their physical, and mostly molecular, properties re presents the largest part of the first two chapters (PH and ions pp. 2 to 47; PH and ions pp. 47 2 to 111). PH is the only compound described in this volume which is thermally stable under normal J conditions. It is the phosphorus analog of ammonia, but exhibits, however, a quite different chemical behavior towards most elements and compounds. The majority of its physical, and in particular spectroscopic, properties have been determined in great detail since the sixties, partially in regard to spectroscopic investigations of the atmospheres of the outer planets.
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