Preface xv
About the Editors xvii
List of Contributors xix
Part I Basics of Corrosion and Prevention 1
1 An Overview of Corrosion 3
Marziya Rizvi
1 Introduction 3
1.1 Basics about Corrosion 3
1.2 Economic and Social Aspect of Corrosion 4
1.3 The Corrosion Mechanism 5
1.4 Classification of Corrosion 8
1.5 Common Methods of Corrosion Control 11
1.6 Adsorption Type Corrosion Inhibitors 13
References 15
2 Methods of Corrosion Monitoring 19
Sheerin Masroor
2.1 Introduction 19
2.2 Methods and Discussion 21
2.3 Conclusion 33
References 33
3 Computational Methods of Corrosion Monitoring 39
Hassane Lgaz, Abdelkarim Chaouiki, Mustafa R. Al-Hadeethi, Rachid Salghi, and Han-Seung Lee
3.1 Introduction 39
3.2 Quantum Chemical (QC) Calculations-Based DFT Method 40
3.3 Atomistic Simulations 45
Acknowledgments 51
Suggested Reading 51
References 51
4 Organýc and Inorganýc Corrosýon Inhýbýtors: A Comparýson 59
Goncagül Serdarog¿lu and Savas¿ Kaya
4.1 Introduction 59
4.2 Corrosion Inhibitors 61
References 69
Part II Heterocyclic and Non-Heterocyclic Corrosion Inhibitors 75
5 Amines as Corrosion Inhibitors: A Review 77
Chandrabhan Verma, M. A. Quraishi, Eno E. Ebenso,and Chaudhery Mustansar Hussain
5.1 Introduction 77
5.2 Conclusion and Outlook 88
Important Websites 89
References 89
6 Imidazole and Its Derivatives as Corrosion Inhibitors 95
Jeenat Aslam, Ruby Aslam, and Chandrabhan Verma
6.1 Introduction 95
6.2 Corrosion Mechanism 96
6.3 Corrosion Inhibitors 97
6.4 Corrosion Inhibitors: Imidazole and Its Derivatives 98
6.5 Computational Studies 110
6.6 Conclusions 113
References 113
7 Pyridine and Its Derivatives as Corrosion Inhibitors 123
Chandrabhan Verma, M. A. Quraishi, and Chaudhery Mustansar Hussain
7.1 Introduction 123
7.2 Summary and Outlook 130
References 140
8 Quinoline and Its Derivatives as Corrosion Inhibitors 149
Chandrabhan Verma and M. A. Quraishi
8.1 Introduction 149
8.2 Quinoline and Its Derivatives as Corrosion Inhibitors 151
8.3 Conclusion and Outlook 160
References 161
9 Indole and Its Derivatives as Corrosion Inhibitors 167
Taiwo W. Quadri, Lukman O. Olasunkanmi, Ekemini D. Akpan, and Eno E. Ebenso
9.1 Introduction 167
9.2 Synthesis of Indoles and Its Derivatives 168
9.3 A Brief Overview of Corrosion and Corrosion Inhibitors 171
9.4 Application of Indoles as Corrosion Inhibitors 172
9.5 Corrosion Inhibition Mechanism of Indoles 201
9.6 Theoretical Modeling of Indole-Based Chemical Inhibitors 202
9.7 Conclusions and Outlook 205
References 207
10 Environmentally Sustainable Corrosion Inhibitors in Oil and Gas Industry 221
M. A. Quraishi and Dheeraj Singh Chauhan
10.1 Introduction 221
10.2 Corrosion in the Oil-Gas Industry 222
10.3 Review of Literature on Environmentally Sustainable Corrosion Inhibitors 223
10.4 Conclusions and Outlook 233
References 235
Part III Organic Green Corrosion Inhibitors 241
11 Carbohydrates and Their Derivatives as Corrosion Inhibitors 243
Jiyaul Haque and M. A. Quraishi
11.1 Introduction 243
11.2 Glucose- Based Inhibitors 244
11.3 Chitosan- Based Inhibitors 246
11.4 Inhibition Mechanism of Carbohydrate Inhibitor 251
11.5 Conclusions 252
References 252
12 Amino Acids and Their Derivatives as Corrosion Inhibitors 255
Saman Zehra and Mohammad Mobin
12.1 Introduction 255
12.2 Corrosion Inhibitors 257
12.3 Why There Is Quest to Explore Green Corrosion Inhibitors? 258
12.4 Amino Acids and Their Derived Compounds: A Better Alternate to the Conventional Toxic Corrosion Inhibitors 261
12.5 Overview of the Applicability of Amino Acid and Their Derivatives as Corrosion Inhibitors 264
12.6 Recent Trends and the Future Considerations 277
12.7 Conclusion 280
Acknowledgments 281
References 281
13 Chemical Medicines as Corrosion Inhibitors 287
Mustafa R. Al-Hadeethi, Hassane Lgaz, Abdelkarim Chaouiki, Rachid Salghi, and Han-Seung Lee
13.1 Introduction 287
13.2 Greener Application and Techniques Toward Synthesis and Development of Corrosion Inhibitors 288
13.3 Types of Chemical Medicine-Based Corrosion Inhibitors 291
13.4 Application of Chemical Medicines in Corrosion Inhibition 292
Acknowledgments 306
References 306
14 Ionic Liquids as Corrosion Inhibitors 315
Ruby Aslam, Mohammad Mobin, and Jeenat Aslam
14.1 Introduction 315
14.2 Inhibition of Metal Corrosion 316
14.3 Ionic Liquids as Corrosion Inhibitors 317
14.4 Conclusion and Future Trends 335
Acknowledgment 336
Abbreviations 336
References 337
15 Oleochemicals as Corrosion Inhibitors 343
F. A. Ansari, Sudheer, Dheeraj Singh Chauhan, and M. A. Quraishi
15.1 Introduction 343
15.2 Corrosion 344
15.3 Significance of Green Corrosion Inhibitors 345
15.4 Overview of Oleochemicals 345
15.5 Literatures on the Utilization of Oleochemicals as Corrosion Protection 349
15.6 Conclusions and Outlook 365
References 366
Part IV Organic Compounds-Based Nanomaterials as Corrosion Inhibitors 371
16 Carbon Nanotubes as Corrosion Inhibitors 373
Yeestdev Dewangan, Amit Kumar Dewangan, Shobha, and Dakeshwar Kumar Verma
16.1 Introduction 373
16.2 Characteristics, Preparation, and Applications of CNTs 374
16.3 CNTs as Corrosion Inhibitors 376
16.4 Conclusion 381
Conflict of Interest 381
Acknowledgment 381
Abbreviations 381
References 382
17 Graphene and Graphene Oxides Layers Application as Corrosion Inhibitors in Protective Coatings 387
Renhui Zhang, Lei Guo, Zhongyi He, and Xue Yang
17.1 Introduction 387
17.2 Preparation of Graphene and Graphene Oxides 388
17.3 Protective Film and Coating Applications of Graphene 390
17.4 The Organic Molecules Modified Graphene as Corrosion Inhibitor 398
17.5 The Effect of Dispersion of Graphene in Epoxy Coatings on Corrosion Resistance 399
17.6 Challenges of Graphene 404
17.7 Conclusions and Future Perspectives 404
References 406
Part V Organic Polymers as Corrosion Inhibitors 411
18 Natural Polymers as Corrosion Inhibitors 413
Marziya Rizvi
18.1 An Overview of Natural Polymers 413
18.2 Mucilage and Gums from Plants 415
18.3 The Future and Application of Natural Polymers in Corrosion Inhibition Studies 429
References 431
19 Synthetic Polymers as Corrosion Inhibitors 435
Megha Basik and Mohammad Mobin
19.1 Introduction 435
19.2 General Mechanism of Polymers as Corrosion Inhibitors 437
19.3 Corrosion Inhibitors - Synthetic Polymers 437
19.4 Conclusion 445
Useful Links 447
References 447
20 Epoxy Resins and Their Nanocomposites as Anticorrosive Materials 451
Omar Dagdag, Rajesh Haldhar, Eno E. Ebenso, Chandrabhan Verma,A. El Harfi, and M. El Gouri
20.1 Introduction 451
20.2 Characteristic Properties of Epoxy Resins 452
20.3 Main Commercial Epoxy Resins and Their Syntheses 453
20.4 Reaction Mechanism of Epoxy/Amine Systems 459
20.5 Applications of Epoxy Resins 461
20.6 Conclusion 471
Abbreviations 471
References 472
Index483
